Conventional power sources encounter difficulties in achieving structural unitization with complex-shaped electronic devices because of their fixed form factors. Here, it is realized that an on-demand conformal Zn-ion battery (ZIB) on non-developable surfaces uses direct ink writing (DIW)-based nonplanar 3D printing. First, ZIB component (manganese oxide-based cathode, Zn powder-based anode, and UV-curable gel composite electrolyte) inks are designed to regulate their colloidal interactions to fulfill the rheological requirements of nonplanar 3D printing, and establish bi-percolating ion/electron conduction pathways, thereby enabling geometrical synchronization with non-developable surfaces, and ensuring reliable electrochemical performance. The ZIB component inks are conformally printed on arbitrary curvilinear substrates to produce embodied ZIBs that can be seamlessly integrated with complicated 3D objects (including human ears). The conformal ZIB exhibits a high fill factor (i.e., areal coverage of cells on underlying substrates, ≈100%) that ensures high volumetric energy density (50.5 mWh cm cell −3), which exceeds those of previously-reported shape-adaptable power sources.
We have demonstrated that thin film transistor backplanes for AMOLED could be fabricated with line‐scan sequential lateral solidification (SLS) process. with 4 μm × 730 mm single laser beamlet, directional and two‐shot SLS processes were carried out to make polycrystalline Si films. The geometry for driving TFTs, which can provide sufficient uniformity of TFT performances, is that the source‐drain direction is perpendicular to the grain growth direction. 14″ WXGA (1366×RGB×768) AMOLEDsfor TV application were fabricated by utilizing different TFT geometry for driving TFTs and switching TFTs. The advantages of the line‐scan SLS system are (1) it can provide higher productivity than the conventional laser system and (2) large displays over 50″ can be manufactured without scan overlap area.
Despite the ever-increasing demand for transparent power sources in wireless optoelectronics, most of them have still relied on synthetic chemicals, thus limiting their versatile applications. Here, a class of transparent nanocellulose paper microsupercapacitors (TNP-MSCs) as a beyond-synthetic-material strategy is demonstrated. Onto semi-interpenetrating polymer network-structured, thiol-modified transparent nanocellulose paper, a thin layer of silver nanowire and a conducting polymer (chosen as a pseudocapacitive electrode material) are consecutively introduced through microscale-patterned masks (which are fabricated by electrohydrodynamic jet printing) to produce a transparent conductive electrode (TNP-TCE) with planar interdigitated structure. This TNP-TCE, in combination with solid-state gel electrolytes, enables on-demand (in-series/in-parallel) cell configurations in a single body of TNP-MSC. Driven by this structural uniqueness and scalable microfabrication, the TNP-MSC exhibits improvements in optical transparency (T = 85%), areal capacitance (0.24 mF cm −2 ), controllable voltage (7.2 V per cell), and mechanical flexibility (origami airplane), which exceed those of previously reported transparent MSCs based on synthetic chemicals.
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