The use of thin-foil, self-propagating thermite reactions to bond components successfully depends on the ability to suppress gas generation and avoid pore formation during the exothermic production of brazes. To study the mechanisms of vapor production in diluted thermites, thin film multilayer Al-Cu-CuO-Cu foils are produced via magnetron sputtering, where the Cu layer thickness is systematically increased from 0 to 100 nm in 25 nm increments. The excess Cu layers act as diffusion barriers, limiting the transport of oxygen from the oxide to the Al fuel, as determined by slow heating differential scanning calorimetry experiments. Furthermore, by adding excess Cu to the system, the temperature of the self-propagating thermite reactions drops below the boiling point of Cu, eliminating the metal vapor production. It is determined that Cu vapor production can be eliminated by increasing the Cu interlayer thickness above 50 nm. However, the porous nature of the final products suggests that only metal vapor production is suppressed via dilution. Gas generation via oxygen release is still capable of producing a porous reaction product.
The ballistic perforation response of knits formed from continuous filament aramid is reported and compared to conventional armor textiles and commodity fabrics. The ballistic experiments consist of 6.0-mm-diameter glass spheres impacted into gelatin-backed targets with areal densities from 200-1000 g/m 2. These ballistic experiments are complemented with quasistatic reverse-perforation experiments to gain insights into deformation and failure for these materials. In-plane stretch experiments are also performed to quantify modulus and strain-tofailure. The results show that, while the ballistic performance of traditional woven textiles is generally superior to knitted aramids, knits formed from continuous filament aramid are significantly better than knits formed from staple yarn. Knitted structures are limited by two main factors: failure of a single yarn tends to lead to catastrophic deconstruction and perforation, and the low in-plane modulus of knits leads to poor lateral stress transfer and energy distribution during higher speed impact. Importantly, however, knits provide significantly more reversible
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