The properties of an oxyfluoride glass ceramic that possesses high transparency after ceramming are described. Approximately 25 vol % of this material is comprised of cubic, fluoride nanocrystals and the remainder is a predominantly oxide glass. When doped with Pr+3, the fluorescence lifetime at 1300 nm is longer than in a fluorozirconate glass, suggesting that a significant fraction of the rare-earth dopant is preferentially partitioned into the fluoride crystal phase. This material has the added advantage of being compatible with ambient air processing.

The quantum efficiency of the 1.3 μm transition in Pr3+ doped oxyfluoride transparent glass ceramics is measured using a self-calibrating fluorescence ratio technique. The measured value of 8%±1% is much higher than expected for Pr3+ in an oxide glass, and is consistent with the incorporation of the Pr3+ ions into the fluoride nanocrystals of the glass ceramic. Measured quantum efficiencies are compared with values calculated using the Judd–Ofelt theory, and it is found that the best agreement is obtained when fractional differences between calculated and measured oscillator strengths are minimized, rather than absolute differences. The Judd–Ofelt analysis is used along with a spectral analysis to show that excited-state absorption should not significantly reduce the gain around 1.3 μm in these materials. The fluorescence ratio technique used to measure the quantum efficiency also provides information about ion–ion interactions at higher concentrations. It is found that the addition of the monovalent dopant Ag+ reduces the tendency of the Pr3+ ions to cluster, allowing higher concentrations of Pr3+ without significant concentration quenching.

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Mixed films of unsubstituted phthalocyaninato copper (H16PcCu) and its perfluorinated derivative (F16PcCu) were prepared by co‐evaporation in different molecular mixtures. The films were analyzed in‐situ by conduction measurements. High admixtures of H16PcCu in F16PcCu films disturbed the charge transport. Optical transmission spectroscopy consequently showed the disturbance of the F16PcCu solid state structure for increased admixtures of H16PcCu. The spectral signatures of both the βbilayer‐structure and the β‐structure of F16PcCu decreased. Low admixtures of H16PcCu increased the conductivity, indicating a successful dopant interaction at widely preserved crystallinity of F16PcCu. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)