The properties of an oxyfluoride glass ceramic that possesses high transparency after ceramming are described. Approximately 25 vol % of this material is comprised of cubic, fluoride nanocrystals and the remainder is a predominantly oxide glass. When doped with Pr+3, the fluorescence lifetime at 1300 nm is longer than in a fluorozirconate glass, suggesting that a significant fraction of the rare-earth dopant is preferentially partitioned into the fluoride crystal phase. This material has the added advantage of being compatible with ambient air processing.

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We report an efficient glass-ceramic fiber laser and show that its slope efficiency (~30%) is not compromised by the presence of Nd-doped fluoride crystals embedded within the core of the single-mode optical fiber. In contrast, the spectroscopy (fluorescence and gain spectrum) of the Nd(3+) ions is dramatically changed by the ceramming process, an indication of strong partitioning of the rare-earth ions into the CdF(2):PbF(2):YF(3) crystal environment. The enormous potential for a new range of optical devices based on transparent glass-ceramic materials is highlighted.

The results of a cutback measurement of a glass-ceramic optical waveguide with single-mode fiber geometry have demonstrated that sub decibels per kilometer losses can be achieved. Difference spectra show that the limit of intrinsic scattering in these two-phase structures ought to be tens of decibels per kilometer.

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