Ni-Fe nanoparticles are observed to exsolve from Ni-substituted Sr 0.95 (Ti 0.3 Fe 0.63 Ni 0.07 )O 3Àd anode. The exsolved nanoparticles act to enhance hydrogen dissociative adsorption, yielding much lower anode polarization resistance and higher cell performance, especially under low pH 2 and temperatures, which is comparable with the current Ni-based cermets.
The high temperature crystal chemistry and oxygen permeation properties of the cation-ordered
LnBaCo2normalO5+δ
perovskite oxides [lanthanide
(Ln)=Pr
, Nd, and Sm] have been investigated in comparison with the cation-disordered
La0.5Ba0.5CoO3−δ
perovskite. The
LnBaCo2normalO5+δ
(
Ln=Pr
, Nd, and Sm) oxides exhibit a metal-insulator transition at
T<200°C
, as evidenced by total conductivity measurements and high temperature X-ray diffraction data and an oxygen vacancy order–disorder transition at
T350°C
in air, as evidenced by an orthorhombic to tetragonal transition. At a given temperature, the oxygen permeation flux decreases from
Ln=La
to Nd to Sm due to the changes in crystal symmetry and lattice strain. The oxygen permeation mechanism in the
Ln=Nd
is bulk-diffusion-limited rather than surface-exchange-limited for membrane thickness
L≥1.1mm
.
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