Aims. In order to understand the observed molecular diversity in high-mass star-forming regions, we have to determine the underlying physical and chemical structure of those regions at high angular resolution and over a range of evolutionary stages. Methods. We present a detailed observational and modeling study of the hot core VLA 3 in the high-mass star-forming region AFGL 2591, which is a target region of the NOrthern Extended Millimeter Array (NOEMA) large program CORE. Using NOEMA observations at 1.37 mm with an angular resolution of ~0″. 42 (1400 au at 3.33 kpc), we derived the physical and chemical structure of the source. We modeled the observed molecular abundances with the chemical evolution code MUSCLE (MUlti Stage ChemicaL codE). Results. With the kinetic temperature tracers CH3CN and H2CO we observe a temperature distribution with a power-law index of q = 0.41 ± 0.08. Using the visibilities of the continuum emission we derive a density structure with a power-law index of p = 1.7 ± 0.1. The hot core spectra reveal high molecular abundances and a rich diversity in complex molecules. The majority of the molecules have an asymmetric spatial distribution around the forming protostar(s), which indicates a complex physical structure on scales <1400 au. Using MUSCLE, we are able to explain the observed molecular abundance of 10 out of 14 modeled species at an estimated hot core chemical age of ~21 100 yr. In contrast to the observational analysis, our chemical modeling predicts a lower density power-law index of p < 1.4. Reasons for this discrepancy are discussed. Conclusions. Combining high spatial resolution observations with detailed chemical modeling allows us to derive a concise picture of the physical and chemical structure of the famous AFGL 2591 hot core. The next steps are to conduct a similar analysis for the whole CORE sample, and then use this analysis to constrain the chemical diversity in high-mass star formation to a much greater depth.

Context. This study is part of the project "CORE", an IRAM/NOEMA large program consisting of observations of the millimeter continuum and molecular line emission towards 20 selected high-mass star forming regions. The goal of the program is to search for circumstellar accretion disks, study the fragmentation process of molecular clumps, and investigate the chemical composition of the gas in these regions. Aims. We focus on IRAS 23385+6053, which is believed to be the least evolved source of the CORE sample. This object is characterized by a compact molecular clump that is IR dark shortward of 24 µm and is surrounded by a stellar cluster detected in the near-IR. Our aim is to study the structure and velocity field of the clump. Methods. The observations were performed at ∼1.4 mm and employed three configurations of NOEMA and additional single-dish maps, merged with the interferometric data to recover the extended emission. Our correlator setup covered a number of lines from well-known hot core tracers and a few outflow tracers. The angular (∼0. 45-0. 9) and spectral (0.5 km s −1 ) resolutions were sufficient to resolve the clump in IRAS 23385+6053 and investigate the existence of large-scale motions due to rotation, infall, or expansion. Results. We find that the clump splits into six distinct cores when observed at sub-arcsecond resolution. These are identified through their 1.4 mm continuum and molecular line emission. We produce maps of the velocity, line width, and rotational temperature from the methanol and methyl cyanide lines, which allow us to investigate the cores and reveal a velocity and temperature gradient in the most massive core. We also find evidence of a bipolar outflow, possibly powered by a low-mass star. Conclusions. We present the tentative detection of a circumstellar self-gravitating disk lying in the most massive core and powering a largescale outflow previously known in the literature. In our scenario, the star powering the flow is responsible for most of the luminosity of IRAS 23385+6053 (∼3000 L ). The other cores, albeit with masses below the corresponding virial masses, appear to be accreting material from their molecular surroundings and are possibly collapsing or on the verge of collapse. We conclude that we are observing a sample of star-forming cores that is bound to turn into a cluster of massive stars.

Aims. Thanks to the high angular resolution, sensitivity, image fidelity, and frequency coverage of ALMA, we aim to improve our understanding of star formation. One of the breakthroughs expected from ALMA, which is the basis of our Cycle 5 ALMA-IMF Large Program, is the question of the origin of the initial mass function (IMF) of stars. Here we present the ALMA-IMF protocluster selection, first results, and scientific prospects. Methods. ALMA-IMF imaged a total noncontiguous area of ~53 pc2, covering extreme, nearby protoclusters of the Milky Way. We observed 15 massive (2.5 −33 × 103 M⊙), nearby (2−5.5 kpc) protoclusters that were selected to span relevant early protocluster evolutionary stages. Our 1.3 and 3 mm observations provide continuum images that are homogeneously sensitive to point-like cores with masses of ~0.2 M⊙ and ~0.6 M⊙, respectively, with a matched spatial resolution of ~2000 au across the sample at both wavelengths. Moreover, with the broad spectral coverage provided by ALMA, we detect lines that probe the ionized and molecular gas, as well as complex molecules. Taken together, these data probe the protocluster structure, kinematics, chemistry, and feedback over scales from clouds to filaments to cores. Results. We classify ALMA-IMF protoclusters as Young (six protoclusters), Intermediate (five protoclusters), or Evolved (four proto-clusters) based on the amount of dense gas in the cloud that has potentially been impacted by H II region(s). The ALMA-IMF catalog contains ~700 cores that span a mass range of ~0.15 M⊙ to ~250 M⊙ at a typical size of ~2100 au. We show that this core sample has no significant distance bias and can be used to build core mass functions (CMFs) at similar physical scales. Significant gas motions, which we highlight here in the G353.41 region, are traced down to core scales and can be used to look for inflowing gas streamers and to quantify the impact of the possible associated core mass growth on the shape of the CMF with time. Our first analysis does not reveal any significant evolution of the matter concentration from clouds to cores (i.e., from 1 pc to 0.01 pc scales) or from the youngest to more evolved protoclusters, indicating that cloud dynamical evolution and stellar feedback have for the moment only had a slight effect on the structure of high-density gas in our sample. Furthermore, the first-look analysis of the line richness toward bright cores indicates that the survey encompasses several tens of hot cores, of which we highlight the most massive in the G351.77 cloud. Their homogeneous characterization can be used to constrain the emerging molecular complexity in protostars of high to intermediate masses. Conclusions. The ALMA-IMF Large Program is uniquely designed to transform our understanding of the IMF origin, taking the effects of cloud characteristics and evolution into account. It will provide the community with an unprecedented database with a high legacy value for protocluster clouds, filaments, cores, hot cores, outflows, inflows, and stellar clusters studies.

The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which, therefore, represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA Large Program FAUST. We detected several lines from methanol and its isopotologues (13CH3OH and CH2DOH), methyl formate and ethanol. Lines are bright toward the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines non-LTE analysis constrains the gas temperature (∼100 K), density (≥1.5 × 108 cm−3), and emitting size (∼10 au in radius). All CH3OH and 13CH3OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on the present work, little chemical evolution from Class 0 to I hot corinos occurs.

Aims. Methanol is a ubiquitous species commonly found in the molecular interstellar medium. It is also a crucial seed species for the building-up of the chemical complexity in star forming regions. Thus, understanding how its abundance evolves during the star formation process and whether it enriches the emerging planetary system is of paramount importance. Methods. We used new data from the ALMA Large Program FAUST (Fifty AU STudy of the chemistry in the disk/envelope system of Solar-like protostars) to study the methanol line emission towards the [BHB2007] 11 protobinary system (sources A and B), where a complex structure of filaments connecting the two sources with a larger circumbinary disk has been previously detected. Results. Twelve methanol lines have been detected with upper energies in the range [45-537] K along with one 13 CH 3 OH transition and one methyl formate (CH 3 OCHO) line blended with one of the methanol transitions. The methanol emission is compact (FWHM ∼ 0.5 ) and encompasses both protostars, which are separated by only 0.2 (28 au). In addition, the overall methanol line emission presents three velocity components, not spatially resolved by our observations. Nonetheless, a detailed analysis of the spatial origin of these three components suggests that they are associated with three different spatial regions, with two of them close to 11B and the third one associated with 11A. A non-LTE radiative transfer analysis of the methanol lines gives a kinetic temperature of [100-140] K, an H 2 volume density of 10 6 -10 7 cm −3 and column density of a few 10 18 cm −2 in all three components with a source size of ∼ 0.15 . Thus, this hot and dense gas is highly enriched in methanol with an abundance as high as 10 −5 . Using previous continuum data, we show that dust opacity can potentially completely absorb the methanol line emission from the two binary objects. Conclusions. Although we cannot firmly exclude other possibilities, we suggest that the detected hot methanol is resulting from the shocked gas from the incoming filaments streaming towards [BHB2007] 11 A and B, respectively. Higher spatial resolution observations are necessary to confirm this hypothesis.