A composite cathode based on redox-stable La0.2Sr0.8TiO(3+δ) (LSTO) can perform direct carbon dioxide electrolysis; however, the insufficient electro-catalytic activity limits the electrode performances and current efficiencies. In this work, catalytically active scandium is doped into LSTO to enhance the electro-catalytic activity for CO2 electrolysis. The structures, electronic conductivities and ionic conductivities of La0.2Sr0.8Ti(1-x)Sc(x)O (LSTS(x)O) (x = 0, 0.05, 0.1, 0.15 and 0.2) are systematically studied and further correlated with electrode performances. The ionic conductivities of single-phase LSTS(x)O (x = 0, 0.05, 0.1 and 0.15) remarkably improve versus the scandium doping contents though the electrical conductivities gradually change in an adverse trend. Electrochemical measurements demonstrate promising electrode polarisation of LSTS(x)O electrodes and increasing scandium doping contents accordingly improve electrode performances. The Faradic efficiencies of carbon dioxide electrolysis are enhanced by 20% with LSTS0.15O in contrast to bare LSTO electrodes in a solid oxide electrolyser at 800 °C.
Advancing clinical and nonclinical diagnostic technologies is particularly crucial for improved preparedness for the next pandemic and other global healthcare challenges. To this end, marrying advanced microscopic imaging with chip‐scale bioanalytical systems provides fresh modalities by analyzing signals of transmitted, reflected, or scattered light waves. This review brings clarity to the latest progress of refractometric imaging and biodetections on a chip, in which interferences and resonances as cornerstones of optics and plasmonics are breaking new ground. A vast range of nanophotonic and plasmonic transducers are discussed, ranging from planar films, nanoarrays, and waveguiding resonators to holistic designs. The augmented bioanalyses cover immunoassays, single‐molecule analysis, and motion tracking of bacterial pathogens and cells. Compared to single‐point spectroscopic measurements, imaging‐empowered approaches are rapidly evolving with greatly promoted signal‐noise ratio, spatial‐temporal resolutions, multiplexability, and throughput, which can be accomplished in a compact cradle system with minimized bulky components in a spectrometer‐free manner. Besides, advances in machine learning technologies applied for data analytics and transducer designs are highlighted. All in all, there are unlimited opportunities for new optical structures, principles, and ways of data retrieval to tap in, which will raise technological impacts on unveiling fundamental issues in life science and advancing global healthcare technologies.
Edge computing, which sinks a large number of complex calculations into edge servers, can effectively meet the requirement of low latency and bandwidth efficiency and can be conducive to the development of the Internet of Vehicles (IoV). However, a large number of edge servers mean a big cost, especially for the 5G scenario in IoV, because of the small coverage of 5G base stations. Fortunately, coherent beamforming (CB) technology enables fast and long-distance transmission, which gives us a possibility to reduce the number of 5G base stations without losing the whole network performance. In this paper, we try to adopt the CB technology on the IoV 5G scenario. We suppose we can arrange roadside nodes for helping transferring tasks of vehicles to the base station based on the CB technology. We first give the mathematical model and prove that it is a NP-hard model that cannot be solved directly. Therefore, we design a heuristic algorithm for an Iterative Coherent Beamforming Node Design (ICBND) algorithm to obtain the approximate optimal solution. Simulation results show that this algorithm can greatly reduce the cost of communication network infrastructure.
Understanding interactions between molecular transition and intense electromagnetic fields confined by plasmon nanostructures is of great significance due to its huge potential in fundamental cavity quantum electrodynamics and practical applications....
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