The anti-corrosion inhibition effect of itraconazole on copper (Cu) in 0.5 M H2SO4 is observed with variety of experimental methods, including electrochemical measurement, surface morphology analysis, and theoretical calculations. These experimental results all confirm that itraconazole exhibits excellent anti-corrosion performance in the certain temperatures range (298 K–313 K) for copper in sulfuric acid solution. In addition, corresponding adsorption isothermal models were used to fit the adsorption behavior of itraconazole on the copper surface. The results show that the Langmuir adsorption model agrees best with the experimental results. The adsorption of itraconazole on the copper surface belongs to chemical and physical adsorption.
1-Hydroxy-7-azabenzotriazole (HOAT) was explored via experimental and theoretical computation methods as a corrosion inhibitor for mild steel in 1 M sulfuric acid. These data indicate that HOAT has good ability to suppress corrosion of the mild steel, with ideal agreement with between experimental and computational results. Besides, the electrochemical experiments show that HOAT is a mixed-type corrosion inhibitor for mild steel in 1 M H 2 SO 4 . Furthermore, HOAT adsorption on the surface of steel conforms to the Langmuir isotherm model. Finally, computational simulation was executed to deeply investigate the mechanism to HOAT inhibition corrosion of steel.
The flame front area is an important parameter to quantify the heat release rate. However, the limitations imposed by the measuring instruments and the measurement methodologies make it difficult to determine the flame front position in an image. This work introduces a method to detect and optimize the flame front boundary. A high‐speed camera was employed to continuously capture the flame images. By setting appropriate intensity thresholds, the impact noise can be eliminated from the image and the flame front boundary can be determined. The binary diagram of the image was morphologically processed to obtain the normalized area fluctuations of the flame front in a temporally resolved manner. Two flame types and combustion regimes were studied. A LABVIEW‐based program was used for the synchronous triggering of the camera, the photomultiplier, and the microphones. The normalized area and photomultiplier output signals of a multiple flame burner obtained within the same period were compared and combined with the spectrum information from the microphone in the cavity. The trend charts were investigated in terms of the Pearson correlation coefficient. The results showed a strong correlation, thereby verifying the feasibility of this method.
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