The activities of MoOz in the (Ti,Mo)Oz solid solution were measured at seven different compositions, using an emf method involving calcia-stabilized zirconia as solid electrolyte. In the temperature range studied, 1350 to 1600 K, the activities of Moo2 show a strong positive deviation from ideal behavior. In addition, the solvus of the Ti02-MoOz system was determined with the equilibration and quenching technique.The solvus maximum was found at T = 1420 2 5 K and X(Mo02) = 0.85 2 0.05.
Fused deposition modeling (FDM) is one of the most common additive manufacturing (AM) techniques for fabricating prototypes as well as functional parts. In this technique, several parameters may influence the part quality and consequently mechanical properties of fabricated components. In this paper, an experimental investigation on effects of fabrication temperature as one of the influential parameters on mechanical properties of manufactured parts is presented. A series of specimens fabricated at temperatures ranging from 180 to 260 • C were used for this investigation. X-ray computed tomography (CT) was used in order to non-destructively analyze the internal geometry of the specimens especially the bond between extruded filaments. Finally, the specimens were subjected to a uniaxial tensile load for evaluation of mechanical properties. The results showed that the specimens fabricated at lower temperatures have relatively lower tensile strength despite their considerably higher strain at break. In addition, the specimens fabricated at higher temperature range had significantly higher tensile strength because of the better bond between extruded filaments. The different mechanical responses were highly related to the internal geometry of the specimens and not necessarily the porosity. CT showed great potential as a non-destructive tool for investigation and development of FDM process.
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