Dolomitic Roman cement was a widely used binder for construction purposes during the late 19th/ early 20th century in territory of Latvia. Because of its hydraulic properties and fast setting it was especially favorable for the usage for the cast elements of Art Nouveau style facades. The production of the material was discontinued in the middle of the 20th century. Nevertheless, there is a need of compatible material for restoration purposes that is not currently commercially available. A compatible binder has been synthesized from mixture of dolomite flour and clay. The research gives an insight of the ongoing chemical processes during the hydration of the cement minerals in the binder. The influence of clay content in compositions and of firing temperature on the physico-chemical properties and mineralogical composition of obtained material is estimated.
Devonian, and Quaternary clays of Latvia together with additive of sawdust after plastic moulding of pellets were used. Partial oxidation of sawdust and formation of active carbon after thermal shock at temperature 800°C were determined. The main clay mineral in all of clays was hydromica with some difference in the structure. Obtained materials with bulk density 1.1 g/cm3 as sorbent for different chemicals such as iodine and methylene blue was used. Dependence of sorption ability of pellets on the type of used clay (clay minerals) was determined. XRD for the determination of phase compositions, nitrogen absorption for the pore size distribution, SEM for the analysis of structure and nanoscale Zetasizer for the determination of surface charge were used.
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