A stabilizing influence: Heterocyclic diaminophosphines can stabilize diphosphineimines sufficiently to allow the preparation of metal complexes. A kinetically stable diphosphineimine is isolated and its coordination chemistry investigated through the preparation of molybdenum (see picture) and nickel complexes with such PPN ligands.
The variation technique may be useful as an alternative instructional approach to enhance beginning chemistry students' mathematics competency and problem-solving ability in both education and practice. [J Nurs Educ. 2017;56(1):22-26.].
Ein stabilisierender Einfluss: Heterocyclische Diaminophosphine können Diphosphinimine ausreichend stabilisieren, um die Synthese von Metallkomplexen zu ermöglichen. Ein kinetisch stabiles Diphosphinimin wurde isoliert, und seine Koordinationschemie wurde anhand der Synthese von Molybdän‐ (siehe Bild) und Nickelkomplexen mit solchen PPN‐Liganden untersucht.
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