Highly regular laser-induced periodic surface structures (HR-LIPSS) have been fabricated on surfaces of Mo, steel alloy and Ti at a record processing speed on large areas and with a record regularity in the obtained sub-wavelength structures. The physical mechanisms governing LIPSS regularity are identified and linked with the decay length (i.e. the mean free path) of the excited surface electromagnetic waves (SEWs). The dispersion of the LIPSS orientation angle well correlates with the SEWs decay length: the shorter this length, the more regular are the LIPSS. A material dependent criterion for obtaining HR-LIPSS is proposed for a large variety of metallic materials. It has been found that decreasing the spot size close to the SEW decay length is a key for covering several cm2 of material surface by HR-LIPSS in a few seconds. Theoretical predictions suggest that reducing the laser wavelength can provide the possibility of HR-LIPSS production on principally any metal. This new achievement in the unprecedented level of control over the laser-induced periodic structure formation makes this laser-writing technology to be flexible, robust and, hence, highly competitive for advanced industrial applications based on surface nanostructuring.
Silicon is one of the most abundant materials which is used in many areas of modern research and technology. A variety of those applications require surface nanopatterning with minimum structure defects. However, the high-quality nanostructuring of large areas of silicon surface at industrially acceptable speed is still a challenge. Here, we report a rapid formation of highly regular laser-induced periodic surface structures (HR-LIPSS) in the regime of strong ablation by infrared femtosecond laser pulses at sub-MHz repetition rate. Parameters of the laser-surface interactions and obtained experimental results suggest an important role of electrostatically assisted bond softening in initiating the HR-LIPSS formation
In this brief review the advances on Direct Laser Patterning (DLP) for the synthesis of photo-luminescent semiconductor quantum dots (QDs) belonging to II-VI groups, especially in solid state using laser-assisted conversion are reported and commented. The chemistry of the precursor synthesis is illustrated because it is a crucial step for the development of the direct laser patterning of QDs. In particular, the analysis of cadmium (bis)thiolate and cadmium xanthates precursors after thermal and laser treatment is examined, with a special focus on the optical properties of the formed QDs. The second part of the review examines how the laser parameters such as the wavelength and pulse duration may regulate the properties of the patterned QDs. The DLP technique does not require complex laser systems or the use of dangerous chemical post treatments, so it can be introduced as a potential method for the patterning of pixels in quantum dot light emitting diodes (QD-LEDs) for display manufacturing.
All periodontal devices used in this in vitro study produced a certain degree of surface alteration. Hand curettes appear to have a major impact on surface integrity compared with piezoelectric ultrasonic devices.
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