Efficiently storing electricity generated
from renewable resources
and desalinating brackish water are both critical for realizing a
sustainable society. Previously reported desalination batteries need
to work in alternate desalination/salination modes and also require
external energy inputs during desalination. Here, we demonstrate a
novel zinc–air battery-based desalination device (ZABD), which
can desalinate brackish water and supply energy simultaneously. The
ZABD consists of a zinc anode with a flowing ZnCl2 anolyte
stream, a brackish water stream, and an air cathode with a flowing
NaCl catholyte stream, separated by an anion-exchange membrane and
a cation-exchange membrane, respectively. During the discharging,
ions in brackish water move to the anolyte and catholyte, and they
return to the feed steam during charging. The ZABD can desalt brackish
water from 3000 ppm to the drinking water level at 120.1 ppm in one
step and concurrently provide an energy output up to 80.1 kJ mol–1 under a discharge current density of 0.25 mA cm–2. Further, the ZABD can be charged/discharged over
20 cycles without significant performance deterioration, demonstrating
its reversibility. Moreover, the desalination performances can be
adjusted by varying current densities and are also influenced by the
initial concentration of salt feeds. Besides, two ZABD devices were
connected in series to drive 60 light-emitting diodes during the salt
removal process without external power supply over 2000 min. Overall,
this ZABD system demonstrates the potential for simultaneous water
desalination and energy supply, which is suitable for many urgent
situations.
A consumption-free electrochemical desalination method is demonstrated to work based on a light-driven photocathode with a Pt/CdS/CZTS/Mo architecture.
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