Quantum tunneling between two plasmonic resonators links nonlinear quantum optics with terahertz nanoelectronics. We describe the direct observation of and control over quantum plasmon resonances at length scales in the range 0.4 to 1.3 nanometers across molecular tunnel junctions made of two plasmonic resonators bridged by self-assembled monolayers (SAMs). The tunnel barrier width and height are controlled by the properties of the molecules. Using electron energy-loss spectroscopy, we directly observe a plasmon mode, the tunneling charge transfer plasmon, whose frequency (ranging from 140 to 245 terahertz) is dependent on the molecules bridging the gaps.

A surface plasmon resonance (SPR) based graphene biosensor is presented. It consists of a graphene sheet coated above a gold thin film, which has been proposed and experimentally fabricated recently [ChemPhysChem 11, 585 (2010)]. The biosensor uses attenuated total reflection (ATR) method to detect the refractive index change near the sensor surface, which is due to the adsorption of biomolecules. Our calculations show that the proposed graphene-on-gold SPR biosensor (with L graphene layers) is (1 + 0.025 L) x gamma (where gamma > 1) times more sensitive than the conventional gold thin film SPR biosensor. The improved sensitivity is due to increased adsorption of biomolecules on graphene (represented by the factor gamma) and the optical property of graphene.

Optical sensors are widely used for refractive index measurement in chemical, biomedical and food processing industries. Due to specific field distribution of the resonances excited, optical sensors provide high sensitivity to ambient refractive index variations. The sensitivity of optical sensor is highly dependent on material and structure of the sensor. Here, we review six major categories of optical refractive index sensors using plasmonic and photonic structures: (i) metal-based propagating plasmonic eigenwave structures, (ii) metal-based localized plasmonic eigenmode structures, (iii) dielectric-based propagating photonic eigenwave structures, (iv) dielectric-based localized photonic eigenmode structures, (v) advanced hybrid structures, and (vi) 2D material integrated structures. Representative configurations working in the wavelength range of 400−2000 nm will be selected and compared in terms of bulk refractive index sensitivities, figure of merits and working wavelengths. A technology map is established in order to define the standard and development trend for optical refractive index sensors.