The development of smart polymer materials is reviewed and illustrated. Important examples of these polymers include conducting polymers, ionic gels, stimulus-response be used polymers, liquid crystalline polymers and piezoelectric materials, which have desirable properties for use in wearable sensors. This review outlines the mode of action in these types of smart polymers systems for utilisation as wearable sensors. Categories of wearable sensors are considered as tattoo-like designs, patch-like, textile-based, and contact lens-based sensors. The advantages and disadvantages of each sensor types are considered together with information on the typical performance. The research gap linking smart polymer materials to wearable sensors with integrated power systems is highlighted. Smart polymer systems may be used as part of a holistic approach to improve wearable devices and accelerate the integration of wearable sensors and power systems, particularly in health care.
In this work, wearable resistive gas sensors based on hybrid graphene/zinc oxide (ZnO) nanocomposites were fabricated on a flexible cotton fabric and employed to monitor odorless and colorless carbon monoxide (CO). Dip-coating and chemical bath deposition (CBD) was used to deposit the graphene layer and grow the ZnO nanorods, respectively. The films were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-Ray diffraction (XRD) to investigate their morphological structures, elemental composition, and crystal phase, respectively. Those characterizations were also confirming the growth of ZnO nanorods on the already-deposited graphene layer on fabrics. From the gas sensor measurements at room temperature, it was revealed that these graphene/ZnO nanocomposites were highly sensitive and selective towards CO gas at low concentration down to 10 ppm. The shortest response and recovery times of the sensors were measured to be 280 s and 45 s, respectively. Moreover, in comparison to bare graphene sensors, the surface modification by ZnO nanorods could obviously enhance the sensing response by up to 40% (i.e., doubled sensitivity). These flexible hybrid sensors are therefore expected to be a promising alternative for the existing rigid CO sensors in the market by offering unique nanostructures, low-cost fabrication, high flexibility, and good sensing performances. INDEX TERMS Wearable gas sensor, carbon monoxide, graphene, zinc oxide, fabric-based sensor.
As a hormone that determinates the level of fruit ripeness, ethylene concentration monitoring plays an important role in the agricultural field. One of the techniques that can be used to detect ethylene concentration is the sensing method. Zinc oxide (ZnO) is a multipurpose metal oxide semiconductor with a wide application in sensing area. Here, we use a ZnO-based flexible sensor to identify the presence of ethylene gas at certain concentrations. The as-synthesized ZnO layers were deposited on a polyethylene terephthalate-indium doped tin oxide (PET-ITO) flexible substrate using a simple electrochemical deposition method. To enhance the performance of the ethylene sensor, a small amount of silver (Ag) was added to the seeding solution. From the study, it was revealed that the ZnO-Ag layers were able to identify the presence of ethylene gas at the lowest concentration of 29 ppm. The most optimal result was obtained using 1 mM Ag. This layer demonstrated a response of 17.2% and 19.6% of ethylene gas at concentrations of 29 and 50 ppm, with recovery times of four and eight minutes, respectively.
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