Electrospinning preparation of perylene-bisimide-functionalized graphene/polylactic acid composite films with shape-memory properties.

In order to enhance the interfacial interactions between the sisal fiber (SF) and the polypropylene (PP) matrix, a water-solubility hyperdispersant which has amphipathic structure and flexible segment was used. Experimental results revealed that when the content of hyperdispersant is 5 percent, the impact strength of the composites was 27.4 kJ·m-2 and the flexural strength of SF/PP composites was 40.1 MPa, which was 64 and 34 wt% higher than that of unmodified systems, respectively. Meanwhile, the crystallinity of the composites also leads to an increase.

A new kind of lower-branched liquid crystalline polyester (LLCP) containing polyester mesogenic units was synthesized by p-hydroxybenzoic acid, terephthalyl chloride and trimellitic anhydride (TMA), then was used as collaborative modifier for the epoxy resin (E-51) with γ-azyl polyhedral oligomeric silsesquioxane (POSS). The experimental results showed that the LLCP / POSS could act as an effective toughening modifier for the epoxy resin. The impact strength of the composites modified with LLCP and POSS was 1.1 times higher than that of the unmodified system. The temperature of starting decomposition and maximum decomposition rate improved about 20 oC and 13 oC , respectively.