The current Venus climate is largely regulated by globally covered concentrated sulfuric acid clouds from binary condensation of sulfuric acid (H2SO4) and water (H2O). To understand this complicated H2SO4‐H2O gas‐cloud system, previous theoretical studies either adopted complicated microphysical calculations or assumed that both H2SO4 and H2O vapor follow their saturation vapor pressure. In this study, we developed a simple one‐dimensional cloud condensation model including condensation, diffusion and sedimentation of H2SO4 and H2O but without detailed microphysics. Our model is able to explain the observed vertical structure of cloud and upper haze mass loading, cloud acidity, H2SO4, and H2O vapor, and the mode‐2 particle size on Venus. We found that most H2SO4 is stored in the condensed phase above 48 km, while the partitioning of H2O between the vapor and clouds is complicated. The cloud cycle is mostly driven by evaporation and condensation of H2SO4 rather than H2O and is about seven times stronger than the H2SO4 photochemical cycle. Most of the condensed H2O in the upper clouds is evaporated before the falling particles reach the middle clouds. The cloud acidity is affected by the temperature and the condensation‐evaporation cycles of both H2SO4 and H2O. Because of the large chemical production of H2SO4 vapor and relatively inefficient cloud condensation, the simulated H2SO4 vapor above 60 km is largely supersaturated by more than two orders of magnitude, which could be tested by future observations.
In the absence of solar radiation, precipitating electrons from the solar wind (SW) are generally thought to be the dominant source of energy deposition in the nightside Martian upper atmosphere, creating a patchy ionosphere and possibly also affecting the nightside thermal budget of various neutral and ionized species. Previous model calculations have not taken into account in situ heating via SW electron impact. In the present study, we utilize extensive measurements made by several instruments on board the Mars Atmosphere and Volatile Evolution spacecraft, in order to perform data-driven computations of the nightside neutral, ion, and electron heating rates. Considering the large range of energetic electron intensity observed on the nightside of Mars, we divide the entire data set into two subsamples, either with or without energetic electron depletion, a notable feature of the nightside Martian ionosphere. Our calculations indicate that in situ nightside neutral heating is dominated by exothermic chemistry and Maxwell interaction with thermal ions for regions with depletion, and by direct SW impact for regions without. Collisional quenching of excited state species produced from a variety of channels, such as electron impact excitation, dissociation, and ionization, as well as dissociative recombination, makes a substantial contribution to neutral heating, except during depletion. For comparison, nightside ion heating is mainly driven by energetic ion production under all circumstances, which occurs mainly via ion-neutral reaction O+ + CO2 and CO2 + predissociation.
The Venusian clouds originate from the binary condensation of H2SO4 and H2O. The two components strongly interact with each other via chemistry and cloud formation. Previous works adopted sophisticated microphysical approaches to understand the clouds. Here, we show that the observed vapour and cloud distributions on Venus can be well explained by a semi-analytical model. Our model assumes local thermodynamical equilibrium for water vapour but not for sulphuric acid vapour, and includes the feedback of cloud condensation and acidity to vapour distributions. The model predicts strong supersaturation of the H2SO4 vapour above 60 km, consistent with our recent cloud condensation model. The semi-analytical model is 100 times faster than the condensation model and 1000 times faster than the microphysical models. This allows us to quickly explore a large parameter space of the sulphuric acid gas-cloud system. We found that the cloud mass loading in the upper clouds has an opposite response of that in the lower clouds to the vapour mixing ratios in the lower atmosphere. The transport of water vapour influences the cloud acidity in all cloud layers, while the transport of sulphuric acid vapour only dominates in the lower clouds. This cloud model is fast enough to be coupled with the climate models and chemistry models to understand the cloudy atmospheres of Venus and Venus-like extra-solar planets.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.