Polytetrafluoroethylene/Poly(methyl methacrylate) (PTFE/PMMA) composite was prepared by mixing PTFE into PMMA matrix which synthesized by the PMMA powder mixture and methyl methacrylate (MMA) liquid mixture. The effects of the filling mass ratio of PTFE and powder/liquid (P/L) ratio on the friction and wear properties of PTFE/PMMA composites against bearing steel were studied by a ball-on-disk tribometer. Fourier transform infrared (FTIR), field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDS) were used to characterize the synthesis of PTFE/PMMA composite. The shore hardness and glass transition temperature (Tg) were obtained respectively by shore hardness tester and differential scanning calorimetry (DSC). The results show that the friction coefficient and wear rate of PMMA based composite, comparing with the unfilled PMMA, can be significantly reduced by filling with PTFE. With the increasing of PTFE filling mass ratio, the wear rate of PTFE/PMMA composite increases. The friction coefficient and wear rate of the unfilled PMMA and PTFE/PMMA composite generally decrease with the P/L ratio increasing. The main wear mechanism of the unfilled PMMA is adhesive wear. While the main wear mechanisms of PTFE/PMMA composites are fatigue wear and abrasive wear.

Orientations and weaves played an important role in the friction reduction and antiwear properties of PTFE/Kevlar fabric composite.

The filling combination of polytetrafluoroethylene (PTFE)/Cu/Al2O3 filled poly(methyl methacrylate) (PMMA) based composites aiming at low friction and wear is optimized based on L9(34) by Taguchi method. The worn morphologies of PMMA based composites are analyzed by scanning electron microscopy (SEM). The PTFE transfer film and the wear debris on the steel ball surface are analyzed by SEM and X‐ray spectroscopy. It is observed that the friction and wear of PMMA can be obviously decreased by filling with PTFE, Cu, and Al2O3. PTFE has the most significant but Cu has the negligibly smallest contribution on both the friction coefficient and the wear rate. The lower friction coefficient (<0.2) appears by the combination of the mass ratio of PTFE larger than about 4.5% and the mass ratio of Al2O3 lower than ∼7.5%. The lower wear rate (<5 × 10−5 mm3/Nm) appears by the combination of the mass ratio of PTFE larger than about 5% and the mass ratio of Al2O3 lower than ∼8%, but it does not include that PTFE is greater than about 8.5% and Al2O3 is less than about 1.5%. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46705.

Wear resistance of PMMA/PTFE composite improved by heat treatment (pressures temperatures, times).

No abstract