Sunlight-induced photodegradation of rhodamine B over
Ag3PO4 has been observed. Nanosized Ag3PO4 was synthesized by a facile ion-exchange route. X-ray
powder diffraction, scanning electron microscopy, X-ray photoelectron
spectroscopy, the Brunauer–Emmett–Teller surface area,
UV–vis diffuse reflectance spectroscopy and photoluminescence
spectra were employed to investigate the phase structure, morphology
and optical property of the Ag3PO4 product.
Nearly 100% of rhodamine B was degraded after a very short irradiation
time using simulated sunlight in Ag3PO4 suspension,
and the total organic carbon measurement revealed that a high degree
of mineralization was achieved in the present photocatalytic system.
Ag3PO4 catalyst has an excellent photocatalytic
performance due to the high separation efficiency of electron and
hole pairs. In the neutral pH solution, Ag3PO4 catalyst exhibited the best photoactivity under simulated sunlight.
The photoinduced holes were considered to be the dominant active species
in the photodegradation process.
We
fabricated a nanowire-channel intrinsically stretchable neuromorphic
transistor (NISNT) that perceives both tactile and visual information
and emulates neuromorphic processing capabilities. The device demonstrated
excellent stretching endurance of 1000 stretch cycles while retaining
stable electrical properties. The device was then applied as a multisensitive
afferent nerve that processes information in parallel. Compatible
with skin deformation, the devices are attached to fingers to serve
as conformal strain sensors and neuromorphic information-processing
units for gesture recognition. The excitatory postsynaptic current
in each device represents shape changes and is then analyzed using
softmax activation processing of the neural network to recognize gestures.
A multistage neural network that uses NISNT was used to further confirm
the gestures. This work demonstrated an idea toward multisensory artificial
nerves and neuromorphic systems.
Chrysanthemum-analogous Bi 2 O 3 -Bi 2 WO 6 composite microspheres, assembled by nanosheets, were synthesized through a one-step hydrothermal route with the aid of surfactant templates. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were employed to clarify the structure and morphology of the Bi 2 O 3 -Bi 2 WO 6 microspheres. Nitrogen adsorption and desorption isotherms were conducted to examine the specific surface area and the pore nature of the as-prepared microspheres. The photocatalytic activity of the Bi 2 O 3 -Bi 2 WO 6 composite microspheres was evaluated by using rhodamine B as a model contaminant, and over 99% of rhodamine B was degraded within 10 min under the exposure of sunlight. The Bi 2 O 3 -Bi 2 WO 6 composite microspheres presented enhanced photocatalytic performances compared with separate Bi 2 O 3 , Bi 2 WO 6 , and conventional P25.
Composites of TiO2-B nanorods and reduced graphene oxide (RGO) were prepared through a simple two-step hydrothermal process followed by subsequent heat treatment in argon. The obtained TiO2-B nanorods had a small size (∼10 nm diameter of the nanorod) and a uniform morphology. Importantly, the synergistic effect of RGO nanosheets and nanostructured TiO2-B leads to electrodes composed of the TiO2-B-RGO nanocomposites which exhibit excellent cycling stability and rate capability (260 mA h g(-1) at 1 C and 200 mA h g(-1) at 2 C after 300 cycles and 140 mA h g(-1) at 20 C).
The design of the first p–i–n junction synaptic transistor (JST) based on n‐type TiO2 film covered with poly(methyl methacrylate) (PMMA) and with a p‐type P3HT/PEO nanowire (NW) on top. Except for basic synaptic functions that can be realized by a single neurotransmitter, the electronic device emulates the multiplexed neurotransmission of different neurotransmissions, i.e., glutamate and acetylcholine, for fast switching between short‐ and long‐term plasticity (STP and LTP). This is realized by the special p–i–n junction with hole transport in the p‐type P3HT NW to form STP, and electron transport in the n‐type TiO2 layer and trapped under the PMMA inversion layer to form LTP. Altering the external input induces changes of the polarity of the charge carriers in the conductive channel, promoting fast switching between STP and LTP modes. When stimulated using two parallel inputs, the response of PMMA/TiO2 emulates the synergistic effect of taste and aroma on the control of food‐intake in the brain. Because of the bipolarity, the p–i–n JST has excellent reconfigurability, which importantly is attributed to simulate the plasticity of synapses and to mimic how distinct types of gustatory receptor neurons respond to different concentrations of salt. The electronic device lays the technical foundation for the realization of the future complex artificial neural networks.
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