Performance of a two-stage biofiltration system was investigated for removal of styrene-acetone mixtures. High steady-state acetone loadings (above C(in)(Ac) = 0.5 g.m(-3) corresponding to the loadings > 34.5 g.m(-3).h(-1)) resulted in a significant inhibition of the system's performance in both acetone and styrene removal. This inhibition was shown to result from the acetone accumulation within the upstream trickle-bed bioreactor (TBR) circulating mineral medium, which was observed by direct chromatographic measurements. Placing a biofilter (BF) downstream to this TBR overcomes the inhibition as long as the biofilter has a sufficient bed height. A different kind of inhibition of styrene biodegradation was observed within the biofilter at very high acetone loadings (above C(in)(Ac) = 1.1 g.m(-3) or 76 g.m(-3).h(-1) loading). In addition to steady-state measurements, dynamic tests confirmed that the reactor overloading can be readily overcome, once the accumulated acetone in the TBR fluids is degraded. No sizable metabolite accumulation in the medium was observed for either TBR or BF. Analyses of the biodegradation activities of microbial isolates from the biofilm corroborated the trends observed for the two-stage biofiltration system, particularly the occurrence of an inhibition threshold by excess acetone.

ABSTRACT

Abstract:

The large-scale plasma treatment of waste gas in industrial or municipal conditions requires high efficiency of plasma conversion process at high processing speed, i.e., large volumetric flow. The integration of the plasma unit into existing systems puts demands on the pipe-system compatibility and minimal pressure drop due to adoption of plasma processing step. These conditions are met at the innovative rotating electrode gliding arc plasma unit described in this article. The system consists of propeller-shaped high voltage electrode inside grounded metallic tube. The design of HV electrode eliminates the pressure drop inside the air system, contrary the plasma unit itself is capable of driving the waste gas at volumetric flow up to 300 m³/hr for 20 cm pipe diameter. In the article the first results on pilot study of waste air treatment will be given for selected volatile organic compounds together with basic characteristic of the plasma unit used.