Only experimentally determined energy levels are included, the energies being restricted to excitations of outer-shell electrons and to inner-shell excitations up to the soft x-ray range. The levels were taken from analyses of the spectra of atomic gases wherever possible; however, the levels for several of the triply ionized rare earths are from analyses of the spectra of the ions in crystals or solutions. In addition to the level value (usually in units of cm 1 ) and the parity, the J value, configuration and term assignments, and the experimental g value are listed wherever available. Leading percentages from the calculated eigenvector are also tabulated for each level if available. The levels are grouped into spectroscopic terms of appropriate coupling schemes where such groups appear meaningful. Ionization potentials are tabulated for most of the spectra. Complete references for the tabulated data are given for each spectrum.
Values of the first four ionization potentials of the lanthanides (Z =57-71) and of Hf have been compiled. All except the value for neutral Hf are based on spectroscopic data. The spectroscopic designations of the ground levels of the neutral through triply ionized atoms (Z =57-72) are also tabulated. A similar compilation for the actinides (Z =89-103) lists Sugar's recent values for the first ionization potentials through No (Z=102). Accurate spectroscopic ionization potentials have been determined for only two of the actinide ions (Ac+ and Th 3 +). The ground-level designations for the neutral through triply ionized actinides are given where they are known or can be predicted with near certainty. A selection of references to the most complete and most recent work on the analyses of the optical spectra of the neutral through triply ionized lanthanide and actinide elements is included.
The bibliography contains approximately 1100 references classified by subject for individual atoms and atomic ions. A number index identifies the references. An author index is included. References included contain data on energy levels, classified lines, wavelengths, Zeeman effect. Stark effect, hyperfine structure, isotope shift, ionization potentials, or theory which gives results for specific atoms or atomic ions.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.