We report new findings on multilayer silicene grown on Si(111)√3 × √3 R30°–Ag template, after the recent first compelling experimental evidence of its synthesis. Low-energy electron diffraction, reflection high-energy electron diffraction, and energy-dispersive grazing incidence X-ray diffraction measurements were performed to show up the fingerprints of √3 × √3 multilayer silicene. Angle-resolved photoemission spectroscopy displayed new features in the second surface Brillouin zone, attributed to the multilayer silicene on Si(111)√3 × √3 R30°–Ag. Band-structure dispersion theoretical calculations performed on a model of three honeycomb stacked layers, silicene grown on Si(111)√3 × √3 R30°-Ag surface confirm the experimental results.
Metallic atomic chains weakly coupled to the substrate may be a practical implementation of extreme onedimensional quantum systems. We report a two-step method of assembling one-dimensional Sb atomic chains on an ordered stepped Si(553) surface with Pb nanoribbons. We show that Pb atoms act as a surfactant, induce the dissociation of Sb molecules, and enable the formation of monatomic chains. Combining atomistic modeling within density functional theory with scanning tunneling microscopy and angle-resolved photoemission spectroscopy, we demonstrate that the formed Sb chains are highly strained and at the same time electronically isolated, exhibiting extremely well-defined one-dimensional free-electron like behavior.
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