Fly ash cenospheres are inexpensive, readily available from coal burning or heavy oil combustion, not an eco-friendly material. If ways can be found to use this, it will serve the twin purposes of facilitating applications for the ash bearing materials and at the same time reduce pollution. One way to achieve this task is to make ash-bearing composites having polymer matrices. The performance of filled polymers is generally determined on the basis of the interface attraction of filler and polymers. Fillers of widely varying particle size and surface characteristics are responsive to the interfacial interactions with the polymers. The present study deals with the effect of particle size (150 mesh, 100 mesh, and 300 mesh) variations in fly ash cenospheres, as a filler with different concentrations (0-40 wt%), on various properties of acrylonitrile butadiene styrene. The mechanical, thermal, and electrical properties of the composite material were evaluated, and the microstructure was investigated through scanning electron microscopy. The smaller particle size showed better properties in comparison with larger particle size. As increasing filler loading, the saturation level is influenced by the agglomeration of filler particles in the polymer matrix. Thus, the performance of polymer filled with fly ash cenosphere composites is the function of the particle size, the dispersion, and the interfacial interaction between the filler particles and the polymer matrix.
Present study deals with the effect of variation in melt flow index (MFI) of maleic anhydride-grafted polypropylene (PP-g-MAH) as a polymeric compatibilizing agent on various properties of fly ash (FA)-filled polypropylene (PP) composites. The FA content was varied from 0 to 40 wt%. The effect of polymeric compatibilizing agents with different MFI and very high maleic anhydride (MAH) content on interfacial adhesion between filler and matrix and filler dispersion were studied. The mechanical and thermal properties of the composite material were evaluated, and the microstructure was investigated through scanning electron microscopy. The values of yield stress and breaking strength of compatibilized PP/PP-g-MAH/FA-based composites showed higher values compared to that of untreated FA-filled PP composites at corresponding filler content. Incorporation of FA into PP led to stiffer materials, as tensile modulus increased significantly. Tensile and impact properties varied with varying molecular weight of PP in PP-g-MAH and are essentially decided by wettability of the filler. It is also found that heatdeflection temperature and vicat softening point improved with the addition of FA filler. The use of PP-g-MAH as polymeric coupling agent provides improvement in mechanical and thermal properties of filled polymers. The higher effect of compatibilization is
With the advent of plastics and the wide range of fillers that are available have made modifications as precise as the tailored resins themselves. To modify the properties of polymer either by using fillers or by preparation of polymer blends gives rise to new materials with tailored properties. More complex, three-component systems, obtained by the addition of polymeric modifier to polymer filled composites may be of interest. Use of Fly ash cenospheres is very attractive because it is inexpensive and its use can reduce the environmental pollution to a significant extent. In the present study, Poly (Methyl Methacrylate) (PMMA)-Fly ash cenospheres composites were prepared using extrusion followed by Injection molding. The effect of matrix modification with Methyl methacrylate-acrylonitrile-butadiene-styrene (MABS) on the performance of PMMA-Fly ash cenospheres compositions was also, studied. It was found that with the addition of Fly ash cenospheres particulate as filler in PMMA showed marginal reduction in Tensile Strength, % Elongation and Impact strength and improvement in Flexural
The advent of plastics and the wide range of fillers that are available have made modification as precise as the tailored resins themselves. Compounds are prepared from poly (methyl methacrylate) (PMMA), and two fillers, talc and synthetic sodium aluminum silicate (SSAS), at varying concentrations (up to 40 wt%). The effects of both the fillers on the mechanical, thermal, and electrical properties, salt spray performance; rheological as well as optical properties of filled PMMA are measured. The impact strength of PMMA increased with increasing concentrations of talc and SSAS up to 20 and 15% loading, respectively, and thereafter declined continuously in both the cases. Increase in impact strength is more in the case of talc-filled PMMA than that of SSAS-filled PMMA. Tensile strength decreased with increasing concentration of both the fillers continuously. The elongation at break decreased drastically for PMMA with increasing concentrations of both the fillers. Electrical properties remained almost unchanged with respect to the concentration of the fillers. The zero shear viscosity increased with increasing concentration of both the fillers, but the rate of increase was more for SSAS than that for talc.
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