Globally conserved phase ordering dynamics is investigated in systems with short range correlations at t = 0. A Ginzburg-Landau equation with a global conservation law is employed as the phase field model. The conditions are found under which the sharp-interface limit of this equation is reducible to the area-preserving motion by curvature. Numerical simulations show that, for both critical and off-critical quench, the equal time pair correlation function exhibits dynamic scaling, and the characteristic coarsening length obeys l(t) ∼ t 1/2 . For the critical quench, our results are in excellent agreement with earlier results. For off-critical quench (Ostwald ripening) we investigate the dynamics of the size distribution function of the minority phase domains. The simulations show that, at large times, this distribution function has a self-similar form with growth exponent 1/2. The scaled distribution, however, strongly differs from the classical Wagner distribution. We attribute this difference to coalescence of domains. A new theory of Ostwald ripening is developed that takes into account binary coalescence events. The theoretical scaled distribution function agrees well with that obtained in the simulations.
Our numerical simulations with the Cahn-Hilliard equation show that coarsening of fractal clusters (FCs) is not a scale-invariant process. On the other hand, a typical coarsening length scale and interfacial area of the FC exhibit power laws in time, while the mass fractal dimension remains invariant. The initial value of the lower cutoff is a relevant length scale. A sharp-interface model is formulated that can follow the whole dynamics of a diffusion controlled growth, coarsening, fragmentation and approach to equilibrium in a system with conserved order parameter.Comment: 4 pages, 4 figures, RevTex, submitted to PR
Context. The tenuous nitrogen (N2) atmosphere on Pluto undergoes strong seasonal effects due to high obliquity and orbital eccentricity, and has recently (July 2015) been observed by the New Horizons spacecraft. Aims. The main goals of this study are (i) to construct a well calibrated record of the seasonal evolution of surface pressure on Pluto and (ii) to constrain the structure of the lower atmosphere using a central flash observed in 2015. Methods. Eleven stellar occultations by Pluto observed between 2002 and 2016 are used to retrieve atmospheric profiles (density, pressure, temperature) between altitude levels of ~5 and ~380 km (i.e. pressures from ~ 10 μbar to 10 nbar). Results. (i) Pressure has suffered a monotonic increase from 1988 to 2016, that is compared to a seasonal volatile transport model, from which tight constraints on a combination of albedo and emissivity of N2 ice are derived. (ii) A central flash observed on 2015 June 29 is consistent with New Horizons REX profiles, provided that (a) large diurnal temperature variations (not expected by current models) occur over Sputnik Planitia; and/or (b) hazes with tangential optical depth of ~0.3 are present at 4–7 km altitude levels; and/or (c) the nominal REX density values are overestimated by an implausibly large factor of ~20%; and/or (d) higher terrains block part of the flash in the Charon facing hemisphere.
The phase field theory of crystal nucleation described in [L. Gránásy, T. Börzsönyi, T. Pusztai, Phys. Rev. Lett. 88, 206105 (2002)] is applied for nucleation in hard-sphere liquids. The exact thermodynamics from molecular dynamics is used. The interface thickness for phase field is evaluated from the cross-interfacial variation of the height of the singlet density peaks. The model parameters are fixed in equilibrium so that the free energy and thickness of the (111), (110), and (100) interfaces from molecular dynamics are recovered. The density profiles predicted without adjustable parameters are in a good agreement with the filtered densities from the simulations. Assuming spherical symmetry, we evaluate the height of the nucleation barrier and the Tolman length without adjustable parameters. The barrier heights calculated with the properties of the (111) and (110) interfaces envelope the Monte Carlo results, while those obtained with the average interface properties fall very close to the exact values. In contrast, the classical sharp interface model considerably underestimates the height of the nucleation barrier. We find that the Tolman length is positive for small clusters and decreases with increasing size, a trend consistent with computer simulations.
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