The structure elucidation of three metabolites herniarin (7-methoxy-2H-chromen-2-one, 1), phytoalexin (5-acetyl-6-hydroxy-2-(1-hydroxy-1-methylethyl)benzofuran, 2), and prestragol (3-(4'-methoxyphenyl)-prop-1,2-diol, 3) isolated from Artemisia dracunculus was determined on the basis of 1D, 2D NMR methods and by an X-ray crystallographic determination.

This paper aims to examine the results of a survey of 292 first-year biology students to evaluate their perception of their learning environment, as well as their ability to handle an educational innovation such as reverse pedagogy and serious gaming integrated into a hybrid learning environment. We also present the approaches and steps that allowed us to validate our statistical study. We used a methodology to validate the instrument developed; using standard parameters, the mean and the standard deviation to describe quantitative data and percentages for qualitative data. The internal consistency of the scales was assessed using the correlation coefficient calculated after a one-factor analysis of variance as well as Cronbach's alpha coefficient (α). The scores show that the items and subscales have good internal consistency. In addition, it shows that the students are fully aware of their learning environment and the difficulties they encounter. They are motivated to embrace our pedagogical innovation. It, therefore, confirms our willingness to implement this pedagogical model for students in the coming years.

Functionalized alkenes were successfully synthesized via a clean procedure in a short time by using a new recycled heterogeneous catalyst prepared from Moroccan oil shale, this catalyst is characterized by different technics such XRD, BET-BJH, MEB-EDS, and TGA, before it’s has been used in the Knoevenagel condensation between different aldehydes and active methylenes. The results showed that coupling the catalyst with ultrasound irradiations could improve the catalytic system in this transformation by achieving the products in a very short time, the results showed clearly that this catalyst could be considered as excellent recyclable support in Knoevenagel condensation.

Radish (raphanus sativus L) is a vegetable very rich in vitamin C and fiber, this plant belonging to the family Brassicacae characterized by their great capacity to accumulate heavy metals such as Chromium. The aim of our work is the study of the effect of Chromium VI on the morpho-physiological parameters of radish and the assessment of health risk related to the bioaccumulation of Cr in the edible parts. The plantation of radish was made on a soil artificially contaminated by 4 concentrations of Cr(VI) (10, 20, 40 and 60ppm). After comparing the results obtained with the results of non-contaminated soil, it is observed that the Cr affects negatively the growth, yield and the content of chlorophyll, On the other hand, it is noticed that there is a slight increase of sugars, proteins and Proline content with the increase of CrVI concentration in the soil, we can explain this increase by the development of defense mechanisms by the radish plant against the stress caused by CrVI. Regarding the bioaccumulation of Cr we found that the concentration of Cr in different parts of radish is too high compared to the recommended daily dose (120µg), so it is not recommended to consume radish grown in areas contaminated by Cr.

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