We describe here the use of liquid-feed flame spray pyrolysis (LF-FSP) to produce high surface area, nonporous, mixed-metal oxide nanopowders that were subsequently subjected to high-throughput screening to assess a set of materials for deNO(x) catalysis and hydrocarbon combustion. We were able to easily screen some 40 LF-FSP produced materials. LF-FSP produces nanopowders that very often consist of kinetic rather than thermodynamic phases. Such materials are difficult to access or are completely inaccessible via traditional catalyst preparation methods. Indeed, our studies identified a set of Ce(1-x)Zr(x)O(2) and Al(2)O(3)-Ce(1-x)Zr(x)O(2) nanopowders that offer surprisingly good activities for both NO(x) reduction and propane/propene oxidation both in high-throughput screening and in continuous flow catalytic studies. All of these catalysts offer activities comparable to traditional Pt/Al(2)O(3) catalysts but without Pt. Thus, although Pt-free, they are quite active for several extremely important emission control reactions, especially considering that these are only first generation materials. Indeed, efforts to dope the active catalysts with Pt actually led to lower catalytic activities. Thus the potential exists to completely change the materials used in emission control devices, especially for high-temperature reactions as these materials have already been exposed to 1500 degrees C; however, much research must be done before this potential is verified.

Mode I near-tip stress fields for elastic perfectly plastic pressure-sensitive materials under plane strain and small-scale yielding conditions are presented. A Coulomb-type yield criterion described by a linear combination of the effective stress and the hydrostatic stress is adopted in the analysis. The finite element computational results sampled at the distance of a few crack opening displacements from the tip show that, as the pressure sensitivity increases, the magnitudes of the normalized radial and hoop stress ahead of the tip decrease, the total angular span of the singular plastic sectors decreases, and the angular span of the elastic sectors bordering the crack surfaces increases. When non-singular T stresses are considered along the boundary layer of the small-scale yielding model, the near-tip stresses decrease as the T stress decreases. The plastic zone shifts toward the crack surfaces as the T stress increases. When the discontinuities of the radial stress and the out-of-plane normal stress along the border between the plastic sector and the elastic sector are allowed, the angular variations of the asymptotic crack-tip fields agree well with those of the finite element computations. Variation of the Q stresses for pressure-sensitive materials can be found from the asymptotic solutions when the plastic zone size ahead of the tip is relatively larger than the crack opening displacement. In addition the T stress is shown to have strong effects on the plastic zone sizes and shapes which could affect the toughening of pressure-sensitive materials.

We have developed an averaging picosecond x-ray streak camera using a dc-biased photoconductive switch as a generator of a high-voltage ramp. The streak camera is operated at a sweep speed of up to 8 ps/mm, shot-to-shot jitter is less than Ϯ1 ps. The streak camera has been used to measure the time history of broadband x-ray emission from an ultrashort pulse laser-produced plasma. Accumulation of the streaked x-ray signals significantly improved the signal-to-noise ratio of the data obtained.