ObjectivesIn order to clarify how different treeing lifetime and tree growth behavior were between epoxy resins and their nanocomposites, laboratory-prepared epoxy/boehmite alumina nanocomposites were subjected to local high electric filed using treeing test cells, and were evaluated on their treeing performances. Both results experimentally obtained are interpreted based on a multi-core model, and some contradiction in explanation is pointed out for further research. A crossover phenomenon was newly found and interpreted in terms of the multi-core model.
ResultsTreeing phenomena in epoxy/alumina nanocomposite were experimentally investigated and explained to some extent in terms of a multi-core model. Role of nano-fillers was discussed and clarified for treeing resistance. Major results are as follows:(1) Alumina nano-fillers are effective to suppress both tree initiation and propagation. Optimum content of the nano-fillers is around 5 wt% at our current manufacturing technology.(2) It was found that there are two kinds of tree growth processes, i.e. thin channel formation and thick channel formation. At high field, the former is followed by the latter.( 3 ) It was elucidated that thin tree channels reach the opposite electrode at high field, but cause no breakdown in both pure epoxy and its nanocomposite. Treeing breakdown takes place, when thick channels bridge a dielectric specimen, as usually anticipated.(4) Tree channels are broadened from thin to thick by partial discharges (PD's) taking place inside the channels. PD products emerge onto the inner surface in nanocomposites, but no PD products are traced in pure epoxy.(5) A crossover phenomenon as shown in Fig. 1 is recognized in tree growth vs. applied voltage characteristics between pure epoxy and its nanocomposite. Selective paths for thin tree channel formation at high field are assumed in the nanocomposite for explanation.(6) Increase in tree initiation threshold is explained by the increase in the height of a barrier between the electrode and the dielectric. This increase is substantiated by the effect of charge redistribution that is considered to be formed near the metal electrode. This charge redistribution must be caused by the collective role of the electric double layers that each of the multi-cores in the multi-core model may possess.(7) Difference in the speed of thin channel formation at high electric field between pure epoxy and its nanocomposite is interpreted by the concept of rather straightforward selective paths. It is suggested that such paths will be effective with the repulsive force caused by charge tails of the electric double layers that the multi-cores of nano-fillers generate.(8) At medium electric field, nano-fillers or multi-cores are considered to work as high permittivity media to invite a tree tip filled with partially ionized conducting gas. This can explain longer tree growth time in nanocomposites than in pure epoxy.(9) Nanocomposites are more erosion-resistant inside the tree channels than pure epoxy, as clarified in s...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.