No abstract

Molecularly imprinted poly 2-(1H-imidazol-2-yl)-4-phenol prepared by suspension polymerization of 2-(1H-imidazol-2-yl)-4-vinylphenol in the presence of selected nitrogen containing compounds showed adsorption selectivity for target nitrogen-containing compounds in fuel oil.

Molecularly imprinted polymer (MIP) nanofibers were prepared by the electrospinning of poly 2-(1H-imidazol-2-yl)-4-phenol (PIMH) in the presence of various nitrogen containing compounds (N-compounds). Molecularly imprinted polymer nanofibers show selectivity for various target model nitrogen-containing compounds with adsorption capacities of 11.7 AE 0.9 mg g À1 , 11.9 AE 0.8 mg g À1 and 11.3 AE 1.1 mg g À1 for quinoline, pyrimidine and carbazole, respectively. Molecular modelling based upon density functional theory (DFT) indicated that hydrogen bond interactions may take place between the lone-pair nitrogen atom of model compounds (quinoline and pyrimidine) and the -OH and -NH groups of the PIMH nanofibers. The adsorption mode followed the Freundlich (multi-layered) adsorption isotherm, which indicated possible nitrogen-nitrogen compound interactions. Molecularly imprinted polymer nanofibers show potential for the removal of nitrogen-containing compounds in fuel.