Nano sized ZSM-5 zeolite samples were synthesized successively from kaolin clay as alumina source having a large amount of quartz (39%) and silicic acid as silica source by hydrothermal treatment with NaOH in the presence of tetrapropylammonium hydroxide as a template. Then the effect of kaolin content, crystallization temperature and time on the size and crystallinity of the products were investigated. The prepared samples were characterized using XRD, SEM, EDS and FT-IR techniques. The results showed that the synthesized ZSM-5 zeolite samples were almost pure and their crystallization was almost complete. The average particle size, as determined by Debye-Scherrer equation, was in the range of 20-42 nm. Increasing kaolin content on crystal size was more effective than increase in crystallization temperature and time. Additional evidences for the nano sized ZSM-5 zeolite were the asymmetric stretch vibration band at 1225 cm -1 in the FT-IR spectra and TEM images. The scanning electron micrographs of the synthesized zeolites showed that they are spherical shape crystals.

Background:Ecstasy is used to improve mood and cordiality; however, based on some reports, it is neurotoxic to human users.Objectives:Because of the euphoria induced by MDMA (3,4-methylenedioxymethamphetamine) on the users, its consumption is increasing in almost all countries. This study was carried out to determine the effects of ecstasy administration in rats’ blood sugar, lipids profile, and liver function tests.Materials and Methods:The experiment was performed using 50 mature Wistar-Albino male rats. The rats were divided into five groups (n = 10). Sham control group (A), received tap water and ordinary rodent diet. The control (B) was administered saline but tests group C, D1, and D2 received single dose and multiple doses of MDMA, respectively. After experimental period, animals were deeply anesthetized by diethyl ether, sacrificed and the blood samples were collected for the evaluation of blood glucose, serum lipid and aspartate transaminase (AST), alanine transaminase (ALT), and alkaline phosphatase (ALK-P). Data were expressed as mean ± SD and statistical difference was considered significant at P < 0.05.Results:In C group, the values of blood sugar (193.8 ± 11.6 mg/dL), low density lipoprotein (LDL) (19.2 ± 7.9 mg/dL), and cholesterol (76.1 ± 10.6 mg/dL), were significantly increased compared with those of control A and B (135 ± 12.7), (140 ± 18.8), and (45.4 ± 9.8), (49.8 ± 2.1) (49.4 ± 10.6) groups. However, aspartate transaminase (AST) and alanine transaminase (ALT) were significantly increased in groups D1 (145.8 ± 14.7 U/L), (91.1 ± 8.1 U/L), and D2 (159.4 ± 13.8 U/L) and (75.4 ± 7.8) compared with those of group A (107.2 ± 8.1), (45.4 ± 9.8), B (79.8 ± 12.1), (49.8 ± 2.1), and C (115.6 ± 17.5), (52.1 ± 7.6 U/L). Cholesterol and LDL increased in groups C and D compared with group A.Conclusions:These results indicated that chronic administration of MDMA affects liver as well as lipoprotein profile in male rats. The exact mechanism of action needs further investigation.

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