A simplified ‘plug-and-play’ approach to aqueous electrochemical atom transfer radical polymerization has been developed. Well-controlled polymerization of PEGA480 (Ɖm = 1.17 – 1.31) is reported under potentiostatic (3-electrodes, undivided cell)...

Aqueous electrochemical atom transfer radical polymerisation (eATRP) can be challenging due to deleterious side reactions leading to the loss of the ω-chain end, increased rates of activation (k¬act) leading to...

Single-barrel scanning electrochemical cell microscopy has been adapted for polymerisation of acrylamide in droplet cells formed at gold electrode surfaces. Localised electrochemical atom transfer radical polymerisation enables controlled synthesis and...