Zero-bias anomaly in one-dimensional ultrathin metallic nanowires AIP Advances 2, 032143 (2012) Influence of electron scatterings on thermoelectric effect ZnO nanowires were grown between two Au electrodes on an Al 2 O 3 -deposited Si wafer. Photoresponse, photoresponse spectrum, and current-voltage (I -V) studies were performed for the investigation into photoconduction mechanism in these nanowires. The photoresponse of the nanowires under the continuous illumination of light with above-or below-gap energies was slow, which indicates that photocurrent in the nanowires is surface-related rather than bulk-related. The photoresponse spectrum represents the above-and below-gap absorption bands for the photocurrents. The I -V characteristics under the illumination of the above-gap light are ohmic, but the characteristics under the illumination of the below-gap light are Schottky. This observation indicates that the above-gap light lowers the potential barrier built in the contact between the ZnO nanowires and electrodes, but that the below-gap light does not lower the potential barrier.
, has been utilized as capacitor dielectrics and gate oxides in memory devices owing to its high dielectric constant, very low permeability, and high thermal conductivity.[1±3] In nanotube-based electronics, the importance of Al 2 O 3 nanotubes will increase, for these tubes will be useful in the fabrication of nanocables, nanojacks, [4] and nanocapacitors.[5] Al 2 O 3 nanotubes have recently been prepared by etching a porous alumina membrane template, [6] by using a carbon nanotube template, [7] or via an electrochemical anodization of Al/Si in dilute sulfuric acid using porous alumina films. [4,5] Nevertheless, these preparation methods have some difficulties in controlling and achieving uniformity of the thickness of the Al 2 O 3 nanotubes. In the study reported here, an easy and convenient route to fabricate Al 2 O 3 nanotubes with conformally uniform thickness using ZnO nanowires as templates was developed. First, ZnO/Al 2 O 3 core/shell nanofibers were prepared by depositing Al 2 O 3 on ZnO nanowires by atomiclayer deposition (ALD), then amorphous Al 2 O 3 nanotubes were fabricated by wet-etching the ZnO core nanowires in the ZnO/Al 2 O 3 core/shell nanofibers. The thickness of the Al 2 O 3 nanotubes was precisely controlled by the number of ALD reaction cycles. A scanning electron microscopy (SEM) image of bare ZnO nanowires, and transmission electron microscopy (TEM) images of a ZnO/Al 2 O 3 core/shell nanofiber and an Al 2 O 3 nanotube are presented in Figure 1. The SEM image of Figure 1a shows a side view of the ZnO nanowires synthesized on a Si substrate by a thermal evaporation procedure; the diameter of the nanowires is in the range of 20±200 nm, and the length is 20±30 lm. In this procedure, a thick polycrystalline ZnO layer was first formed on the Si substrate by thermal evaporation of ZnO powder, and the ZnO nanowires were then COMMUNICATIONS 422
White-colored materials synthesized by a thermal annealing of milled GaN powders at 930 °C in a nitrogen atmosphere were identified to be monoclinic β-Ga2O3 nanowires by x-ray diffraction and scanning electron microscopy. High-resolution transmission electron microscopy revealed that these nanowires are single nanocrystals, and energy dispersive x-ray indicated that these nanomaterials are free of any metals. In addition, bundles of these crystalline nanowires in the rectangular-pole shape are a few centimeters in length.
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