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Predicting the availability and quality of freshwater resources is a pressing concern in the Mediterranean area, where a number of agricultural systems depend solely on precipitation. This study aims at predicting streamflow and nonpoint pollutant loads in a temporary river system in the Mediterranean basin (Sulcis area, Sardinia, Italy). Monthly discharge, suspended sediment, nitrate nitrogen, total nitrogen, mineral phosphorus, and dissolved oxygen in-stream monitoring data from gauge stations were used to calibrate and validate the Soil and Water Assessment Tool model for the period 1979–2009. A Sequential Uncertainty Fitting procedure was used to auto-calibrate parameter uncertainties and model evaluation. Monthly simulation during the validation period showed a positive model performance for streamflow with Nash–Sutcliffe efficiency and percent bias values of 0.7% and 18.7%, respectively. The simulation results at a watershed level indicate that the sediment load was 1.13 t ha−1 year−1, while for total nitrogen and total phosphorus, the simulated values were 4.8 and 1.18 kg ha−1 year−1, respectively. These results were consistent with the values of soil and nutrient losses observed in the Mediterranean area, although hot-spot areas with high nutrient loadings were identified. The calibrated model could be used to assess long-term impacts on water quality associated with the simulated land use scenarios.

Bioenergy represents the highest share of renewable energies consumed in the European Union and is still expected to grow. This could be possible by exploring bioenergy production on Marginal, Underutilised, and Contaminated lands (MUC) that are not used for agricultural purposes and therefore, present no competition with food/feed production. In this paper, the viability and sustainability of bioenergy value chains on these lands is investigated and measures for market uptake were developed. Using three case study areas in Italy, Ukraine, and Germany, a screening of MUC lands was conducted, then an agronomic assessment was performed to determine the most promising crops. Then, techno-economic assessments followed by sustainability assessments were performed on selected value chains. This concept was then automated and expanded through the development of a webGIS tool. The tool is an online platform that allows users to locate MUC lands in Europe, to define a value chain through the selection of bioenergy crops and pathways, and to conduct sustainability assessments measuring a set of environmental, social, and economic sustainability indicators. The findings showed positive results in terms of profitability and greenhouse gas emissions for bioethanol production from willow in Ukraine, heat and power production from miscanthus, and biogas and chemicals production from grass in Germany. The webGIS tool is considered an important decision-making tool for stakeholders, which gives first insights on the viability and sustainability of bioenergy value chains.

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