Hybrid organic-inorganic perovskites have emerged as very promising materials for photonic applications, thanks to the great synthetic versatility that allows to tune their optical properties. In the two-dimensional (2D) crystalline form, these materials behave as multiple quantum-well heterostructures with stable excitonic resonances up to room temperature. In this work strong lightmatter coupling in 2D perovskite single-crystal flakes is observed, and the polarization-dependent exciton-polariton response is used to disclose new excitonic features. For the first time, an outof-plane component of the excitons is observed, unexpected for such 2D systems and completely absent in other layered materials, such as transition-metal dichalcogenides. By comparing different hybrid perovskites with the same inorganic layer but different organic interlayers, it is shown how the nature of the organic ligands controllably affects the out-of-plane exciton-photon coupling. Such vertical dipole coupling is particularly sought in those systems, e.g. plasmonic nanocavities, in which the direction of the field is usually orthogonal to the material sheet. Organic interlayers are shown to affect also the strong birefringence associated to the layered structure, which is exploited in this work to completely rotate the linear polarization degree in only few microns of propagation, akin to what happens in metamaterials.
Thinning down the absorber layer of GaAs solar cells can reduce their cost and improve their radiation hardness, which is important for space applications. However, the lighttrapping schemes necessary to achieve high absorptance in these cells can be experimentally challenging or introduce various parasitic losses. In this work, a facile light‐trapping approach based on wet chemical etching is demonstrated. The rear‐side contact layer of ultrathin GaAs solar cells is wet‐chemically textured in between local Ohmic contact points using an NaOH‐based etchant. The resulting contact layer morphology is characterized using atomic force microscopy and scanning electron miscroscopy. High broadband diffuse reflectance and haze factors are measured on bare and Ag‐coated textured contact layers. The textured contact layer is successfully integrated as a diffusive rear mirror in thin‐film solar cells comprising a 300‐nm GaAs absorber and Ag rear contact. Consistent increases in short‐circuit current density (JSC) of approximately 3 mA cm−2 (15%) are achieved in the textured cells, while the open‐circuit voltages and fill factors do not suffer from the textured rear mirror. The best cell achieves a JSC of 24.8 mA cm−2 and a power conversion efficiency of 21.4%. The textured rear mirror enhances outcoupling of luminescence at open circuit, leading to a strong increase in the external luminescent efficiency.
A systematic analysis of photonic bands and group index in silicon grating waveguides is performed, in order to optimize band-edge slow-light behavior in integrated structures with low losses. A combination of numerical methods and perturbation theory is adopted. It is shown that a substantial increase of slow light bandwidth is achieved when decreasing the internal width of the waveguide and the silicon thickness in the cladding region. It is also observed that a reduction of the internal width does not undermine the performance of an adiabatic taper.
Most grating couplers for silicon photonics are designed to match the approximately 10 μm mode-field diameter (MFD) of single-mode telecom fibres. In this letter, we analyse grating-coupler designs in the Silicon-on-Insulator (SOI) platform in a wide range of MFDs (4–100 μm) and related footprints, to give a physical understanding of the trends in efficiency and lineshape of the corresponding coupling spectra. We show that large-footprint grating couplers have an intrinsic Lorentzian lineshape that is determined by the quasi-guided photonic modes (or guided resonances) of the corresponding photonic crystal slab, while small-footprint grating couplers have a Gaussian lineshape resulting from the k-space broadening of the incident mode. The crossover between the two regimes is characterized by Voigt lineshapes. Multi-objective particle-swarm optimisation of selected small-footprint apodized grating-couplers is then used to locate the “Pareto fronts;” along which the highest coupling efficiency is achieved for a given bandwidth. This approach identifies several high-efficiency 220 nm SOI grating coupler designs with 1 dB bandwidths exceeding 100 nm. Such grating couplers are ideally suited for broadband photonic applications, such as wavelength-division multiplexing and environmental sensing, and are compatible with commercially available ultra-high numerical aperture fibres
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