Despite the steric hindrance of the central atom in [TaCl 2 (NPh)Cp*] (Ph = C 6 H 5 , Cp* = g 5 -C 5 (CH 3 ) 5 ), caused by the Cp* ligand, the imido-ligand takes a change in bond structure when this educt is reduced to the binuclear com-plex [{TaCl(l-NPh)Cp*} 2 ] in which tantalum is stabilized in the unusual oxidation state +4.
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