Supramolecular short-peptide assemblies have been widely used for the development of biomaterials with potential biomedical applications. These peptides can self-assemble in a multitude of chiral hierarchical structures triggered by the application of different stimuli, such as changes in temperature, pH, solvent, etc. The self-assembly process is sensitive to the chemical composition of the peptides, being affected by specific amino acid sequence, type, and chirality. The resulting supramolecular chirality of these materials has been explored to modulate protein and cell interactions. Recently, significant attention has been focused on the development of chiral materials with potential spintronic applications, as it has been shown that transport of charge carriers through a chiral environment polarizes the carrier spins. This effect, named chiralityinduced spin selectivity or CISS, has been studied in different chiral organic molecules and materials, as well as carbon nanotubes functionalized with chiral molecules. Nevertheless, this effect has been primarily explored in homochiral systems in which the chirality of the medium, and hence the resulting spin polarization, is defined by the chirality of the molecule, with limited options for tunability. Herein, we have developed heterochiral carbon-nanotube−shortpeptide materials made by the combination of two different chiral sources: that is, homochiral peptides (L/D) + glucono-δlactone. We show that the presence of a small amount of glucono-δ-lactone with fixed chirality can alter the supramolecular chirality of the medium, thereby modulating the sign of the spin signal from "up" to "down" and vice versa. In addition, small amounts of glucono-δ-lactone can even induce nonzero spin polarization in an otherwise achiral and spin-inactive peptide− nanotube composite. Such "chiral doping" strategies could allow the development of complementary CISS-based spintronic devices and circuits on a single material platform.

Making use of the combination of multiparametric Fluorescence Lifetime Imaging Microscopy (FLIM) and single-molecule Fluorescence Lifetime Correlation Spectroscopy (FLCS), we have been able to study early stages of Fluorenylmethyloxycarbonyl-diphenylalanine (Fmoc-FF)...

Molecular functionalization of CNTs is a routine procedure in the field of nanotechnology. However, whether and how these molecules affect the spin polarization of the charge carriers in CNTs are largely unknown. In this work we demonstrate that spin polarization can indeed be induced in two-dimensional (2D) CNT networks by “certain” molecules and the spin signal routinely survives length scales significantly exceeding 1 μm. This result effectively connects the area of molecular spintronics with that of carbon-based 2D nanoelectronics. By using the versatility of peptide chemistry, we further demonstrate how spin polarization depends on molecular structural features such as chirality as well as molecule–nanotube interactions. A chirality-independent effect was detected in addition to the more common chirality-dependent effect, and the overall spin signal was found to be a combination of both. Finally, the magnetic field dependence of the spin signals has been explored, and the “chirality-dependent” signal has been found to exist only in certain field angles.

One contribution of 17 to a theme issue 'Heterogeneous materials: metastable and non-ergodic internal structures'.

The mechanism of co-assembly of different aromatic dipeptides has been studied using a combination of microscopy and spectroscopy techniques. At an equimolar ratio, the kinetics of the process is favored giving rise to alternate copolymers.