Considering
the serious impact caused to the environment by the
inappropriate disposal of waste motor oils, it is essential to find
alternative mechanisms to handle and dispose these wastes in a controlled
process. The reuse of waste motor oil as a resource for the synthesis
of diesel-like fuels provides an alternative way for the disposal
of this residue in a feasible, sustainable, and environmentally responsible
way. This work addresses the kinetic study of the catalytic cracking
of waste motor oil using mesoporous aluminum silicate materials impregnated
with 1 and 2% zinc. Both the waste motor oil and liquid fuel product
were characterized according to ASTM standards to ensure an adequate
characterization and to guarantee the proper quality of the product.
The results from the overall kinetic approach show that the cracking
reaction can be described using a first-order rate equation with respect
to the concentration of the used motor oil. The activation energy
for the thermal cracking reaction is 370 kJ/mol. It is reduced by
22% to 287 kJ/mol when the alumina silicate catalysts are used. Also,
during the reaction, the overall yield of the reaction with respect
to the liquid fuel is increased from 63% during the thermal reaction
to 90% during the catalytic reaction.
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