No abstract

The rheological behavior of highly filled ethylene propylene diene rubber (EPDM) compounds was studied with respect to the effect of curative system, grafted rubber, shear rate, temperature and die swell using a Monsanto Processability Tester (MPT) to gain an understanding of the molecular parameters that control the surface finish. All systems show pseudoplastic behavior. At a particular shear rate, shear viscosity increases with blend ratio. The dependence of flow behavior on extrusion velocity indicates a surface effect. The extrudate die swell and maximum recoverable deformation are related by a linear relationship, which is independent of sulfur/accelerator ratio, extrusion temperature and shear rates and blend ratio. The principal normal stress difference increases nonlinearly with shear stress. Activation energy decreases with shear rate in most cases. The faster relaxing system produces extrudate of better surface quality.

In this work, natural and Fe(III)

This paper investigates the effects of surface microgeometry on coating thickness, both theoretically and experimentally. In the theoretical part of the paper, surface roughness parameters are analyzed and basic definitions and general requirements on coating quality defined. The experimental part of the paper gives a calculation for the coating quantity required in order to fill “dead volume” depending on surface roughness. Coating distribution is analyzed using scanning electronic microscopy (SEM). The paper also evaluates quality of a measuring system using magnetic method for measuring coating thickness.