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[1] The recent determination of the gravity field of Mercury and new Earth-based radar observations of the planet's spin state afford the opportunity to explore Mercury's internal structure. These observations provide estimates of two measures of the radial mass distribution of Mercury: the normalized polar moment of inertia and the fractional polar moment of inertia of the solid portion of the planet overlying the liquid core. Employing Monte Carlo techniques, we calculate several million models of the radial density structure of Mercury consistent with its radius and bulk density and constrained by these moment of inertia parameters. We estimate that the top of the liquid core is at a radius of 2020 AE 30 km, the mean density above this boundary is 3380 AE 200 kg m À3 , and the density below the boundary is 6980 AE 280 kg m À3 . We find that these internal structure parameters are robust across a broad range of compositional models for the core and planet as a whole. Geochemical observations of Mercury's surface by MESSENGER indicate a chemically reducing environment that would favor the partitioning of silicon or both silicon and sulfur into the metallic core during core-mantle differentiation. For a core composed of Fe-S-Si materials, the thermodynamic properties at elevated pressures and temperatures suggest that an FeS-rich layer could form at the top of the core and that a portion of it may be presently solid.

Saturn's moon Enceladus harbours a global water ocean , which lies under an ice crust and above a rocky core . Through warm cracks in the crust a cryo-volcanic plume ejects ice grains and vapour into space that contain materials originating from the ocean. Hydrothermal activity is suspected to occur deep inside the porous core, powered by tidal dissipation . So far, only simple organic compounds with molecular masses mostly below 50 atomic mass units have been observed in plume material. Here we report observations of emitted ice grains containing concentrated and complex macromolecular organic material with molecular masses above 200 atomic mass units. The data constrain the macromolecular structure of organics detected in the ice grains and suggest the presence of a thin organic-rich film on top of the oceanic water table, where organic nucleation cores generated by the bursting of bubbles allow the probing of Enceladus' organic inventory in enhanced concentrations.

Radio tracking of the MESSENGER spacecraft has provided a model of Mercury's gravity field. In the northern hemisphere, several large gravity anomalies, including candidate mass concentrations (mascons), exceed 100 milli-Galileos (mgal). Mercury's northern hemisphere crust is thicker at low latitudes and thinner in the polar region and shows evidence for thinning beneath some impact basins. The low-degree gravity field, combined with planetary spin parameters, yields the moment of inertia C/MR(2) = 0.353 ± 0.017, where M and R are Mercury's mass and radius, and a ratio of the moment of inertia of Mercury's solid outer shell to that of the planet of C(m)/C = 0.452 ± 0.035. A model for Mercury's radial density distribution consistent with these results includes a solid silicate crust and mantle overlying a solid iron-sulfide layer and an iron-rich liquid outer core and perhaps a solid inner core.

[1] Neutral particle dominance over charged particles in Saturn's magnetosphere was evident prior to Cassini's arrival at Saturn in 2004. The observation of active plumes emanating from the south pole of Enceladus suggests that this small moon is likely to be the principal source of neutrals in Saturn's magnetosphere. Cassini has flown through the plumes on several occasions, and the resulting data imply the source rate is variable (∼10 27 to 10 28 water molecules/s). Here we use Cassini plasma spectrometer and Cassini magnetospheric imaging instrument observations to update neutral particle lifetimes and then use the most recent processed versions of Cassini ion neutral mass spectrometer observations made during encounters E2, E3, and E5 to constrain a 3-D multispecies neutral particle model. This procedure improves constraints on the plume source rate, ejection velocity, and plume divergence. We find that the plume source rate varies by at least a factor of 4 over the 7 month period considered. Additionally, we find that previous estimates of the plume source rates based on E2 observations are most likely overestimated because the background neutral torus has not been adequately account for. On the basis of these results, we discuss the implications of this variability on global neutral particle distributions.