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Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.

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