In this study, the application of hydrodynamic cavitation to improve the biodegradability of mature landfill leachate was investigated. Three configurations of cavitation device were examined and operational parameters of the process were selected. The study indicated that the orifice plate with a 3/10mm diameter conical concentric hole, characterized by the cavitation number of 0.033, is a reasonable choice to ensure the enhanced biodegradability of mature leachate. Using such a configuration and maintaining 30 recirculation passes through the cavitation zone at inlet pressure of 7 bar, the highest increase of biodegradability index (BI) of approximately 22% occurred, i.e., from the value of 0.046 to 0.056. The FT-IR/PAS analysis confirmed a degradation of refractory compounds that typically prevail in mature leachate. An evaluation of energy efficiency was made in terms of the actual consumed energy measured by using the Kyoritsu KEW6310 Power Quality Tester. A cavitational yield of 9.8 mg COD kJ(-1) was obtained for the optimum configuration and 30 recirculation passes. Regarding energy efficiency, the application of 10 cavitation cycles appeared to be the most profitable. This was due to an almost threefold higher cavitational yield of 27.5 mg COD kJ(-1). However, the preferable option should be selected by considering a satisfactory effect in the biodegradability enhancement.
The present study examines the effect of introducing dried brewery spent grain (BSG), known as the main solid by-product of the brewery industry on biogas yields and kinetics in co-digestion with sewage sludge (SS). The experiment was conducted in semi-continuous anaerobic reactors (supplied once a day) operating under mesophilic conditions (35°C) at different hydraulic retention times (HRT) of 18 and 20 d. In co-digestion runs, the BSG mass to the feed volume ratio was constant and maintained 1:10.The results indicated that the addition of BSG did not influence the biogas production, by comparison with SS mono-digestion (control run). At HRT of 18 d, in the co-digestion run, the average methane yield was 0.27 m3 kg/VSadded, while in the control run the higher value of 0.29 m3 kg/VSaddedwas observed. However, there was no difference in terms of statistical significance. At HRT of 20 d, the methane yield was 0.21 m3 kg/VSadded for both mono- and co-digestion runs. In the BSG presence, the decrease in kinetic constant values was observed. As compared to SS mono-digestion, reductions by 21 and 35% were found at HRT of 20 and 18 d, respectively. However, due to the supplementation of the feedstock with BSG rich in organic compounds, the significantly enhanced energy profits were achieved with the highest value of approx. 40% and related to the longer HRT of 20 d. Importantly, the mono- and co-digestion process proceeded in stable manner. Therefore, the anaerobic co-digestion of SS and BSG might be considered as a cost-effective solution that could contribute to the energy self-efficiency of wastewater treatment plants (WWTPs) and sustainable waste management for breweries.
Membrane techniques constitute an interesting alternative to conventional activated sludge systems (CAS). In membrane bioreactors (MBR), the biomass separated on membranes is retained independently of sludge sedimentation properties. As a consequence, a high biomass concentration as well as low food to microorganisms ratio can be obtained. Moreover, the development of a characteristic activated sludge population is stimulated by the specific conditions prevailing in MBRs. In the study, the operation and treatment efficiency of the MBR and CAS processes were examined and compared. Simulation was performed with the use of GPS-X software. The effluent quality obtained for the MBR system was either better or comparable to that of CAS. The most significant difference concerned the elimination of total suspended solids, which amounted to 99.8% in the MBR. Regarding nutrients, a low concentration of total phosphorus in the effluent from CAS and MBR was obtained (0.67 gP m−3 and 0.50 gP m−3, respectively). Greater differences were achieved in the case of total nitrogen. Although almost complete nitrification took place in both systems, a lower concentration of nitrate in the effluent from MBR in comparison to CAS, i.e., 11.2 gN m−3 and 14.1 gN m−3, respectively, allowed us to obtain a higher removal of total nitrogen (80.8% and 76.1%, respectively).
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