No abstract

Soil structure and organic matter are important indicators of soil quality. In the literature it states that there is a linear relation between soil structure and the organic matter. Mechanisms of formation and stabilization of aggregates have also been described in the literature, but it is evident that not every mechanism is applicable to various soil-climatic conditions. Recently, the modern but not the new term has become a biochar. It is anticipated that biochar is a significant source of C, and its application to the soil will improve the aggregation process in the soil. Lately we have been working in this area and we wanted to provide an overview of this issue through this review. The aim of this review was to collate and synthesize available information on soil structure and SOM. The emphasis of this review is on biochar and its combination with other organic and mineral fertilizers in relation to soil structure.

Since biochar is considered to be a significant source of carbon, in this work we have evaluated the changes in soil organic matter (SOM) and soil structure due to application of biochar and biochar with N fertilization, and have considered the interrelationships between the SOM parameters and the soil structure. The soil samples were collected from Haplic Luvisol at the locality of Dolná Malanta (Slovakia) during 2017. The field experiment included three rates of biochar application (B0-no biochar, B10-biochar at the rate of 10 t ha-1 , B20-biochar at the rate of 20 t ha-1) and three levels of N fertilization (N0-no nitrogen, N160-nitrogen at the rate of 160 kg ha-1 , N240-nitrogen at the rate of 240 kg ha-1). The rate of biochar at 20 t ha-1 caused an increase in the organic carbon (C org) content. The combination of both rates of biochar with 160 and 240 kg N ha-1 also caused an increase in C org. In the case of B20 the extractability of humic substances carbon (C HS) was 17.79% lower than at B0. A significant drop was also observed in the values of the extraction of humic acids carbon (C HA) and fulvic acids carbon (C FA) after the addition of biochar at a dose of 20 t ha-1 with 160 kg N ha-1. However, both rates of biochar had a significant effect at 240 kg N ha-1. After application of 20 t ha-1 of biochar the content of water-stable macro-aggregates (WSA ma) significantly increased compared to control. This rate of biochar also increased the mean weight diameter (MWD W) and the index of water-stable aggregates (Sw) and decreased the coefficient of vulnerability (Kv). The biochar at a rate of 20 t ha-1 with 240 kg N ha-1 the value of MWD W increased and value of Kv decreased significantly. The contents of C org and C L correlated positively with WSA ma , MWD W and Sw and negatively with WSA mi and Kv. The extraction of C HA and C FA was in negative relationship with MWD W. We conclude that the application of biochar and biochar combined with N fertilizer had a positive influence on SOM and soil structure.

Recent studies show that biochar improves physical properties of soils and contributes to the carbon sequestration. In contrast to most other studies on biochar, the present study comprise a long-term field experiment with a special focus on the simultaneous impact of N-fertilizer to soil structure parameters and content of soil organic carbon (SOC) since SOC has been linked to improved aggregate stability. However, the question remains: how does the content of water-stable aggregates change with the content of organic matter? In this paper we investigate the effects of biochar alone and in a combination with N-fertilizer (i) on the content of water-stable macro- (WSAma) and micro-aggregates (WSAmi) as well as soil structure parameters; and (ii) on the contents of SOC and labile carbon (CL) in water-stable aggregates (WSA). A field experiment was conducted with different biochar application rates: B0 control (0 t ha−1), B10 (10 t ha−1) and B20 (20 t ha−1) and 0 (no N), 1st and 2nd level of nitrogen fertilization. The doses of level 1 were calculated on required average crop production using the balance method. The level 2 included an application of additional 100% of N in 2014 and additional 50% of N in the years 2015–2016 on silty loam Haplic Luvisol at the study site located at Dolná Malanta (Slovakia). The effects were investigated after the growing season of spring barley, maize and spring wheat in 2014, 2015 and 2016, respectively. The results indicate that the B10N0 treatment significantly decreased the structure vulnerability by 25% compared to B0N0. Overall, the lower level of N combined with lower doses of biochar and the higher level of N showed positive effects on the average contents of higher classes of WSAma and other soil structure parameters. The content of SOC in WSA in all size classes and the content of CL in WSAma 3–1 mm significantly increased after applying 20 t ha–1 of biochar compared to B0N0. In the case of the B20N1 treatment, the content of SOC in WSAma within the size classes >5 mm (8%), 5–3 mm (19%), 3–2 mm (12%), 2–1 mm (16%), 1–0.5 mm (14%), 0.5–0.25 mm (9%) and WSAmi (12%) was higher than in B0N1. We also observed a considerably higher content of SOC in WSAma 5–0.5 mm and WSAmi with the B10N1 treatment as compared to B0N1. Doses of 20 t biochar ha−1 combined with second level of N fertilization had significant effect on the increase of WSAma and WSAmi compared to the B0N2 treatment. A significant increase of CL in WSA was determined for size classes of 2–0.25 mm and WSAmi in the B20N2 treatment. Our findings showed that biochar might have beneficial effects on soil structure parameters, SOC, CL in WSA and carbon sequestration, depending on the applied amounts of biochar and nitrogen.

In this paper we investigate the effects of biochar alone and its reapplication and combination with N-fertilizer (1) on the soil pH, and (2) sorption parameters. The soil samples were taken during growing period in 2018 from plots with different biochar (first application in 2014 – A, reapplication in 2018 – B) at application rates: 0 t.ha−1 (B0 control), 10 t.ha−1 (B10) and 20 t.ha−1 (B20) and different nitrogen fertilization: N0 (no nitrogen) and N40 (40 kg.ha−1). Our results showed that the first application of biochar at the rate of 20 t.ha−1 (B20A) without N-fertilizer significantly increased the values of soil pH in H2O, soil pH in KCl, the sum of base cations (SBC) and cation exchange capacity (CEC) compared to control (B0). Similar effects were observed also after reapplication of biochar (B10B). All investigated parameters in fertilized control treatment (B0N40) were worst and the first application, as well as the reapplication of biochar with N, caused significant increase of soil pH in H2O, soil pH in KCl, SBC, CEC, BS and decrease of hydrolytic acidity.