In this work, silicon/carbon composites for anode electrodes of Li-ion batteries are prepared from Elkem’s Silgrain® line. Gentle ball milling is used to reduce particle size of Silgrain, and the resulting Si powder consists of micrometic Si with some impurities. Silicon/carbon composite with CMC/SBR as a dual binder can achieve more than 1200 cycles with a capacity of 1000 mAh g−1 of Si. This excellent electrochemical performance can be attributed to the use of a buffer as a solvent to control the pH of the electrode slurry, and hence the bonding properties of the binder to the silicon particles. In addition, the use of FEC as an electrolyte additive is greatly contributing to a stabilized cycling by creating a more robust SEI layer. This work clearly demonstrates the potential of industrial battery grade silicon from Elkem.

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It is known that silicon is an indirect band gap material, reducing its efficiency in photovoltaic applications. Using surface plasmons in metallic nanoparticles embedded in a solar cell has recently been proposed as a way to increase the efficiency of thin-film silicon solar cells. The dipole mode that dominates the plasmons in small particles produces an electric field having Fourier components with all wave numbers. In this work, we show that such a field creates electron-hole-pairs without phonon assistance, and discuss the importance of this effect compared to radiation from the particle and losses due to heating.