Terrestrial planets with large water inventories are likely ubiquitous and will be among the first Earth-sized planets to be characterized with upcoming telescopes. It has previously been argued that waterworlds-particularly those possessing more than 1% H 2 O-experience limited melt production and outgassing due to the immense pressure overburden of their overlying oceans, unless subject to high internal heating. But an additional, underappreciated obstacle to outgassing on waterworlds is the high solubility of volatiles in high-pressure melts. Here, we investigate this phenomenon and show that volatile solubilities in melts probably prevent almost all magmatic outgassing from waterworlds. Specifically, for Earth-like gravity and oceanic crust composition, oceans or water ice exceeding 10-100 km in depth (0.1-1 GPa) preclude the exsolution of volatiles from partial melt of silicates. This solubility limit compounds the pressure overburden effect as large surface oceans limit both melt production and degassing from any partial melt that is produced. We apply these calculations to Trappist-1 planets to show that, given current mass and radius constraints and implied surface water inventories, Trappist-1f and -1g are unlikely to experience volcanic degassing. While other mechanisms for interior-surface volatile exchange are not completely excluded, the suppression of magmatic outgassing simplifies the range of possible atmospheric evolution trajectories and has implications for interpretation of ostensible biosignature gases, which we illustrate with a coupled model of planetary interior-climate-atmosphere evolution.

The search for life on exoplanets is motivated by the universal ways in which life could modify its planetary environment. Atmospheric gases such as oxygen and methane are promising candidates for such environmental modification due to the evolutionary benefits their production would confer. However, confirming that these gases are produced by life, rather than by geochemical or astrophysical processes, will require a thorough understanding of planetary context, including the expected counterfactual atmospheric evolution for lifeless planets. Here, we evaluate current understanding of planetary context for several candidate biosignatures and their upcoming observability. We review the contextual framework for oxygen and describe how conjectured abiotic oxygen scenarios may be testable. In contrast to oxygen, current understanding of how planetary context controls non-biological methane (CH 4 ) production is limited, even though CH 4 biosignatures in anoxic atmospheres may be readily detectable with the James Webb Space Telescope. We assess environmental context for CH 4 biosignatures and conclude that abundant atmospheric CH 4 coexisting with CO 2 , and CO:CH 4 « 1 is suggestive of biological production, although precise thresholds are dependent on stellar context and sparsely characterized abiotic CH 4 scenarios. A planetary context framework is also considered for alternative or agnostic biosignatures. Whatever the distribution of life in the Universe, observations of terrestrial exoplanets in coming decades will provide a quantitative understanding of the atmospheric evolution of lifeless worlds. This knowledge will inform future instrument requirements to either corroborate the presence of life elsewhere or confirm its apparent absence.

Recent atmospheric models for brown dwarfs suggest that the existence of clouds in substellar objects is not needed to reproduce their spectra, nor their rotationally induced photometric variability, believed to be due to the heterogeneous cloud coverage of brown dwarf atmospheres. Cloud-free atmospheric models also predict that their flux should not be polarized, as polarization is produced by the light scattering of particles in the inhomogeneous cloud layers of brown dwarf atmospheres. To shed light on this dichotomy, we monitored the linear polarization and photometric variability of the most variable brown dwarf, 2MASS J21392676+0220226. We used FORS2 at the UT1 telescope to monitor the object in the z band for six hours, split on two consecutive nights, covering one-third of its rotation period. We obtained the Stokes parameters, and we derived its time-resolved linear polarization, for which we did not find significant linear polarization (P = 0.14% ± 0.07%). We modeled the linear polarimetric signal expected assuming a map with one or two spot-like features and two bands using a polarization-enabled radiative transfer code. We obtained values compatible with the time-resolved polarimetry obtained for 2MASS J21392676+0220226. The lack of significant polarization might be due to photometric variability produced mostly by banded structures or small-scale vortices, which cancel out the polarimetric signal from different regions of the dwarf’s disk. Alternatively, the lack of clouds in 2MASS J21392676+0220226 would also explain the lack of polarization. Further linear polarimetric monitoring of 2MASS J21392676+0220226, during at least one full rotational period, would help to confirm or discard the existence of clouds in its atmosphere.