To prepare the eco-friendly fire retardant wood, Japanese red pine (Pinus densiflora), Hemlock (Tsuga heterophylla), and Radiata pine (Pinus radiata) were treated with inorganic chemicals, such as sodium silicate, boric acid, ammonium phosphate, and ammonium borate. Different combination and concentration of those chemicals were impregnated by vacuum/pressure treatment methods. The electron-beam treatment was used to increase the chemical penetration into the wood. The fire performance of the fire retardant treated wood was investigated. The penetration of chemicals into the wood was enhanced after electron beam treatment. Ignition time of the treated wood was the most effectively retarded by sodium silicate, ammonium phosphate, and ammonium borate. The most effective chemical combination was found at 50% sodium silicate and 3% ammonium borate, which satisfied flammability criteria for a fire retardant material in the KS F ISO 5660-1 standards.Keywords : eco-friendly fire retardant wood, sodium silicate, ammonium borate, electron beam

No abstract

This study evaluated the ability of white and brown rot fungi to decompose fire retardant-treated wood by measuring mass loss. Anti efficacy of FRT against sapstain and mold fungi was evaluated. Wood was treated with liquid sodium silicate and boric acid, ammonium borate, di-ammonium phosphate. Retardant treated wood was then subjected to fungal decay resistance tests performed according to KS standard method using a brown-rot fungus, Fomitopsis palustris and white rot fungus Trametes versicolor. Aspergillus niger, Penicillium funiculosum, Rhizopus nigricans, Aureobasidium pullulans, Tricoderma virede fungi were used anti-sapstain and mold test. Boron and phosphorus chemicals used in this study increased the resistance of fire retardant treated wood against both fungal attack. Anti mold and sapstain efficacy of the fire 손동원⋅강미란⋅이동흡⋅박상범-560-retardant treated wood was excellent but there were difference depend on mold. After the liquid sodium silicate treatment, the second chemical treatment process could lead chemical fixation into wood, which effects decay resistance.

This study was conducted to examine the functionality of the fire retardant treated wood. The hygroscopic property, leaching resistance, metal corrosive efficacy and gas toxicity of retardant treated wood were analyzed. Sodium silicate was penetrated to the wood for making fire retardant treated wood. The subsequent treatment agents such as boric acid, ammonium borate, di-ammonium phosphate were treated after sodium silicate treatment due to fixation. As results for the test, the leaching resist was improved by subsequent treatment. The fire retardant combination such as sodium silicate, boric acid and di-ammonium phosphate showed high hygroscopic property, metal corrosive efficacy. The gas toxicity was also satisfied KS standard.

The aim of this study is to analyze the combustion and thermal properties in order to establish baseline data for the fire safety evaluation of domestic timbers. The combustion properties such as heat release rate, total heat release, gas yield, and mass loss were analyzed by the method of cone calorimeter test and thermogravimetry (TGA). Thermal decomposition temperatures of the specimens by TGA were recorded as 359.83℃ for White pine, 359.80℃ for Red-Leaved Hornbeam, 363.14℃ for Carolina poplar, 358.59℃ for Konara oak, and 362.11℃ Sargent cherry. Red-Leaved Hornbeam showed the highest value of heat release rate, but, Carolina poplar wood showed the lowest value. In case of the total heat release, Red-Leaved Hornbeam wood showed the highest value and Carolina poplar wood showed the lowest one. The gas analysis results showed that Sargent cherry wood had the lowest value of 0.021, and Konara oak had the highest at 0.031 in the CO/CO 2 . The minimum value of mass reduction was recorded as 87.57% for Sargent cherry, but, on the other hand, it was 95.03% for Konara oak. There was a correlation between the gas generation of CO and CO 2 , and combustion behavior of woods. These results are expected to be usful for providing a fundamental guideline with the fire safety of wood use in interior applications.