There has been an increasing trend in drug resistance in recent years, particularly in retreatment cases. Hence, revision of the national TB control program, reevaluation of the role of the World Health Organization category II (CAT II) regimen, as well as the conducting of a nationwide drug resistance survey, are recommended.
Nowadays, the LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) cathode material has attracted great research interest due to its high energy density and less usage of costly raw materials. However, the high nickel content of NCM811 brings about an extremely unstable interface between the electrode and electrolyte and therefore inferior cyclic stability. Herein, we have proposed a straightforward method to deliver 1, 2, and 4 wt % of TiO 2 nanoparticles (NPs) on the surface of the NCM811 cathode material and to improve its properties at room and high temperatures. Based on scanning electron microscopy and transmission electron microscopy observations, the coating thickness varies from 10 to 35 nm and the 2 wt % TiO 2 -coated cathode is provided with uniformly distributed NPs that could result in an improved structural stability and electrochemical performance. In detail, at 25 and 55 °C and 1 C, the 2 wt % TiO 2 -coated cathode shows capacity retentions of 90.0 and 80.5% after 100 cycles, higher than those of pristine and coated cathodes. Under a high current rate of 10 C at 25 and 55 °C, the discharge capacities of the 2 wt % TiO 2 -coated cathode were 135.9 and 141.4 mA h g −1 , which are significantly higher than those of the pristine cathode material (128.3 and 89.1 mA h g −1 ). Results of the dissolution test at 55 °C reflect the effectiveness of the TiO 2 coating in maintaining the structural integrity of the cathode material and protecting it from HF attack and deleterious side reactions. Also, the differential scanning calorimetry result proves the enhanced safety after surface modification; the TiO 2 coating shifts the exothermic peak of the electrode from 231.1 to 242.9 °C. Therefore, surface modification with TiO 2 NPs can be proposed as a practical and cost-effective method for the commercial application of the high energy density NCM811 cathode at room and high temperatures. KEYWORDS: LiNi 0.8 Co 0.1 Mn 0.1 O 2 , nanocoating, TiO 2 , safety, cathode, lithium-ion batteries
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.