In this study, some properties of cold pressed Cu-B4C composites were investigated. Commercial copper powders with 40 µm particle size were reinforced with B4C in a 40µm particle size at ratios of 0, 1, 2, 3 wt.% for improving mechanical properties of copper used for electrical conductivity. Cu-B4C composites have been fabricated by powder following sintering process. The presence of Cu and B4C which are dominant components in the sintered composites were confirmed by X-ray diffraction analyses technique and SEM-EDS. Scanning electron microscope (SEM-EDS) was showed that B4C particles are distributed homogenously in the copper matrix. The relative densities of Cu and Cu-B4C composites sintered at 700°C are ranged from 97.5% to 90.19%. Microhardness of composites ranged from 80.65 to 87.5 HB and the electrical conductivity of composites changed between 90.04 %IACS and 68.87 %IACS. It was observed that cold pressed Cu-1 wt.% B4C composites revealed promising physical properties.
The pilot-scale treatability of olive oil mill wastewater (OOMW) by physicochemical methods, ultrafiltration and advanced oxidation processes (AOPs) was investigated. Physicochemical methods (acid cracking, oil separation and coagulation-flocculation) showed high efficiency of chemical oxygen demand (COD) (85%), oil and grease (O&G) (> 97%), suspended solids (SS) (> 99%) and phenol (92%) removal from the OOMW. Ultrafiltration followed by physicochemical methods is effective in reducing the SS, O&G. The final permeate quality is found to be excellent with over 90% improvements in the COD and phenol parameters. AOPs (ozonation at a high pH, O3/UV, H2O2/UV, and O3/H2O2/UV) increased the removal efficiency and the O3/H2O2/UV combination among other AOPs studied in this paper was found to give the best results (> 99% removal for COD, > 99% removal for phenol and > 99% removal for total organic carbon). Pilot-scale treatment plant has been continuously operated on site for three years (3 months olive oil production campaign period of each year). The capital and operating costs of the applied treatment alternatives were also determined at the end of these seasons. The results obtained in this study have been patented for 7 years by the Turkish Patent Institute.
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