The problem of a particle in a one-dimensional infinite square-well potential with one wall moving at constant velocity is treated by means of a complete set of functions which are exact solutions of the time-dependent Schrödinger equation. Comparison is made with a first-order perturbation treatment, and numerical results are presented for a particle initially in the ground state.
An equation of state for water, applicable in the pressure range 25 kilobars to 250 kilobars, is formulated in terms of experimental data obtained from shock wave measurements. This equation of state is used to calculate P-V relations for several adiabats and isotherms. Thermodynamic and hydrodynamic data along the Hugoniot curve are given as a function of shock pressure, and pressure-particle velocity relations for initial shocks followed by reflected shocks and rarefactions are given.
High explosives were used to drive strong shock waves into various liquids, and a moving-image camera was employed to determine velocities associated with the shock waves. The measured velocities are transformed to pressure-compression points by applying the conservation relations. The pressures attained vary among the 15 liquids studied but are typically in the range 50 kilobars to 150 kilobars. For water, more extensive experimentation suffices to determine the Hugoniot curve from 30 kilobars to 450 kilobars. The highest pressure for each of the liquids extends the available data range from static experimentation several fold.
A shock-wave-reflection experimental method is described, the purpose of which is to measure the useful thermodynamic variable (ΔH/ΔV)P at high pressures. Results are given for water.
Qualitative experiments to study the transparency of shocked water, carbon tetrachloride, ethyl alcohol, and benzene are reported.
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