Hybrid
capacitive deionization (HCDI) is an emerging and promising
technology for water desalination and has been extensively explored
in recent years. Designing a structure-tailorable electrode material
has been proved to be a valid strategy for achieving a higher salt
adsorption capacity (SAC). In this study, MnO2 materials
with tailorable phase compositions and crystallinities were prepared
hydrothermally and then evaluated as electrodes for removal of ions
from a NaCl solution in a membrane-free HCDI cell. MnO2 electrode materials tested in the HCDI system include poorly crystalline
δ-MnO2 along with abundant amorphous phases (MnO2-1h); crystalline δ-MnO2 with plentiful amorphous
MnO2 (MnO2-2h); MnO2 mixtures of
α-, δ-, and amorphous MnO2 (MnO2-5h); and α-MnO2 nanowires with minor amorphous
MnO2 (MnO2-12h). Our results revealed that the
phase composition and the crystallinity of MnO2 materials
govern their specific capacitances and thus the SAC values. When the
cell voltage is 1.2 V, the lamellar-structured poorly crystalline
MnO2-1h electrode with the lowest crystallinity demonstrates
the highest SACs of 13.84 mg g–1 in 100 mg L–1 NaCl (1.71 mM) and 21.32 mg g–1 in 500 mg L–1 NaCl (8.56 mM) solutions, respectively.
The desalination efficiencies of the MnO2−1h electrode
are remarkable and much greater than other MnO2-based electrodes
under similar conditions (e.g., NaCl concentrations, cell voltage,
etc.). This study sheds light on the significance of understanding
the fundamentals of both the phase composition and crystallinity in
defining the desalination performance of MnO2 electrodes.
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ANO1, anoctamin 1(also known as TMEM16A), is the molecular basis of calcium-activated chloride channels with ten transmembrane segments which are widely expressed in mammalian cells, including epithelial cells, vascular smooth muscle tissues, electro-excitatory cells, and some tumor cells. These proteins are widely expressed in mammalian cells, including epithelial cells, vascular smooth muscle tissues, electro-excitatory cells, and some tumor cells. To date, multiple studies have shown that many natural and synthetic compounds have regulatory effects on ANO1. Therefore, ANO1 could be a potential new drug target for the treatment of cancer, pain, diarrhea, hypertension, and asthma. Here we review the structure of ANO1 and its involvement in cancer, pain, diarrhea, hypertension, and asthma.
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