An increasing number of electromagnetic (EM) sensors are deployed to measure volumetric soil water content (θ) for agricultural, ecological, and geotechnical applications. While impedance and capacitance sensors generally operate at frequencies between 20–300 MHz, time domain‐reflectometry (TDR) and‐transmissometry (TDT) function in the GHz range. In general, lower frequency sensors are less expensive but more sensitive to confounding effects of salinity, temperature, and soil textural variations. To simplify sensor application, factory‐supplied calibrations are often provided for different porous media types such as mineral, organic, and saline soils, or soilless‐substrates. The objective of the presented study was to evaluate the performance of eight commercially available EM moisture sensing systems (TDR 100, CS616, Theta Probe, Hydra Probe, SM300, Wet2, 5TE, 10HS) in seven well‐characterized and texturally varying soils using a standardized approach. The validity of factory supplied‐calibration relationships was evaluated and the influence of soil properties on the EM responses for θ measurements was observed. Results indicate that the factory‐supplied calibration relationships for groups of mineral and organic soils in general performed well, but some inconsistences were identified and suggestions for improvement are discussed. Soil‐specific calibrations from this study yielded accuracies of around 0.015 m3m−3 for 10HS, SM300, and Theta Probe, while lower accuracies of about 0.025 m3 m−3 were found for TDR100, CS616, Wet2, 5TE, and the Hydra Probe. These results are based on mineral soils having a large variation in texture, electrical conductivities below 2 dS m−1, organic matter below 10%, and specific surface areas of less than 50 m2 g−1.

The dry end of the soil water characteristic (SWC) is important for modeling vapor flow dynamics and predicting soil properties such as specific surface area (SSA) and clay content (CL). Verification of new instrumentation for rapid measurement of the dry end of the SWC is relevant to avoid long equilibration times and potential for hydraulic decoupling. The objectives of this study were to measure both adsorption and desorption branches of the dry end of the SWC for 21 variably‐textured Arizona soils using new, fully automated instrumentation (AquaSorp); apply the data to parameterize the Tuller and Or (TO) and new single‐parameter non‐singularity (SPN) models; and evaluate estimates of SSA from water sorption, ethylene glycol monoethyl ether (EGME), and N2–BET methods. The AquaSorp successfully measured water sorption isotherms (∼140 data points) within a reasonably short time (1–3 d). The SPN model well described the distinct non‐singularity between the adsorption and desorption branches, while the TO model captured the adsorption data reasonably well (<5% deviation from measurements), except for matric potentials below –200 MPa. The SSA derived from water sorption and the TO model were comparable to SSAEGME for all soils. The matric potential at “zero” water content was confirmed as the widely accepted value of around –800 MPa. A non‐singularity coefficient based on water adsorption at monolayer coverage was positively correlated with CL. Obtained results show the potential of the AquaSorp to accurately measure the dry region of the SWC, providing a rapid determination of SSA.

Abstract. Fire is a common ecosystem perturbation that affects many soil properties. As global fire regimes continue to change with climate change, we investigated thermal alteration of soils' physical and chemical properties after they are exposed to a range of temperatures that are expected during prescribed and wildland fires. For this study, we used topsoils collected from a climosequence transect along the western slope of the Sierra Nevada that spans from 210 to 2865 m a.s.l. All the soils we studied were formed on a granitic parent material and had significant differences in soil organic matter (SOM) concentration and mineralogy owing to the effects of climate on soil development. Topsoils (0-5 cm depth) from the Sierra Nevada climosequence were heated in a muffle furnace at six set temperatures that cover the range of major fire intensity classes (150, 250, 350, 450, 550 and 650 • C). We determined the effects of heating temperature on soil aggregate strength, aggregate size distribution, specific surface area (SSA), mineralogy, pH, cation exchange capacity (CEC), and carbon (C) and nitrogen (N) concentrations. With increasing temperature, we found significant reduction of total C, N and CEC. Aggregate strength also decreased with further implications for loss of C protected inside aggregates. Soil pH and SSA increased with temperature. Most of the statistically significant changes (p < 0.05) occurred between 350 and 450 • C. We observed relatively smaller changes at temperature ranges below 250 • C. This study identifies critical temperature thresholds for significant physico-chemical changes in soils that developed under different climate regimes. Our findings will be of interest to studies of inferences for how soils are likely to respond to different fire intensities under anticipated climate change scenarios.

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