The contribution that the technique of ferromagnetic resonance (FMR) has made to the understanding of the magnetic behaviour of ultrathin single films is reviewed. Experimental methods to measure FMR in situ in ultrahigh vacuum are presented. The temperature dependence of the magnetization, of the magnetic relaxation rate in the vicinity of the Curie temperature, and of the second-and fourth-order magnetic anisotropy energy (MAE) constants can be measured by FMR in situ for magnetic monolayers. Using the cases of Ni/Cu(001) and Gd/W( 110) as examples, the role of the MAE for the quantitative description of temperature-and thickness-dependent reorientation transitions of the magnetization is discussed. Initial results for the anisotropy of the g-factor which is related to the anisotropy of the orbital moment (and the MAE) are presented.
A new class of highly fluorescent, photostable, and magnetic core/shell nanoparticles in the submicrometer size range has been synthesized from a modified Stöber method combined with the layer‐by‐layer (LbL) assembly technique. Luminescent magnetic nanoparticles are prepared via two main steps. The first step involves controlled addition of tetraethoxysilane to a dispersion of Fe3O4/γ‐Fe2O3 nanoparticles, which are thereby homogeneously incorporated as cores into monodisperse silica spheres. The second step involves the LbL assembly of polyelectrolytes and luminescent CdTe quantum dots onto the surfaces of the silica‐coated magnetite/maghemite particles, which are finally covered with an outer shell of silica. These spherical particles have a typical diameter of 220 ± 10 nm and a saturation magnetization of 1.34 emu g–1 at room temperature, and exhibit strong excitonic photoluminescence. Nanoparticles with such a core/shell architecture have the added benefit of providing a robust platform (the outer silica shell) for incorporating diverse functionalities into a single nanoparticle.
The alignment of multiwalled carbon nanotubes (MWNTs) has been accomplished through deposition of uniform layers of magnetite/maghemite nanoparticles (diameter = 6-10 nm) and use of an external magnetic field. The coating of CNTs with magnetic nanoparticles was performed by combining the polymer wrapping and layer-by-layer (LbL) assembly techniques. The particle-coated MWNTs are superparamagnetic and can be aligned at room temperature on any substrate by deposition from an aqueous solution in an external field B = 0.2 T. The volume magnetization of the particle coated MWNTs is found to be enhanced by 17% compared to the pure particles in a powder indicating that either the adsorption process onto the CNTs changes the particle magnetization, or the MWNTs carry an intrinsic magnetization due to remaining Ni used as a catalyst for the growth process.
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